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休眠-唤醒剂对水泥水化调控影响的研究

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本文研究了蔗糖(SU)作为水泥休眠剂,通过抑制水泥早期水化反应来延缓凝结时间,同时掺入硫酸铝(AS)和甲酸钙(CF)作为唤醒剂,以恢复水泥的正常水化过程.探讨休眠-唤醒处理对水泥浆体及水化产物的影响及作用机理.试验结果表明,添加0.1%SU可以有效抑制水泥浆体的水化,而掺入AS和CF可以消除蔗糖的缓凝效果.AS和CF的复掺可以进一步加速水泥的水化,恢复其正常凝结时间.X射线衍射(XRD)和热重分析(TG-DTG)结果表明,经过休眠-唤醒处理后,水泥早期水化产物的生成得到了有效促进,并提升砂浆的抗压强度.当2.0%AS和1.5%CF复掺时,砂浆的抗压强度达到最佳,3 d和7 d的增幅分别为21.0%、25.7%,试验结果为废水泥砂浆的回收再利用提供了相关理论支撑和参考依据.
This study investigates sucrose(SU)as a cement dormancy agent to delay the setting time by inhibiting the early hydration reaction of cement.Simultaneously,aluminum sulfate(AS)and calcium formate(CF)are introduced as activators to restore the normal hydration process of the cement.The research explores the effects and mechanisms of the dormancy-activation treatment on cement paste and hydration products.The experimental results demonstrate that the addition of 0.1%SU effectively suppresses the hydration of cement paste,while the incorporation of AS and CF counteracts the retarding effect of SU.The combined use of AS and CF further accelerates cement hydration,restoring its normal setting time.X-ray diffraction(XRD)and thermogravimetric analysis(TG-DTG)results reveal that the dormancy-activation treatment effectively promotes the formation of early hydration products,enhancing the compressive strength of mortar.When 2.0%AS and 1.5%CF are co-added,the compressive strength of the mortar reaches the optimum,with increases of 21.0%and 25.7%at 3 days and 7 days respectively.The experimental results provide relevant theoretical support and reference basis for the recycling and reuse of waste cement mortar.

dormancy agentawakening agentsetting timecement hydrationcompressive strength

王成龙、王亮、刘玉亭

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安徽理工大学 土木建筑学院,安徽 淮南 232001

休眠剂 唤醒剂 凝结时间 水泥水化 抗压强度

2025

水泥
建筑材料工业技术情报研究所

水泥

影响因子:0.085
ISSN:1002-9877
年,卷(期):2025.(1)