商丘师范学院学报2024,Vol.40Issue(9) :31-35.

D-π-A型三联吡啶衍生物及其锌配合物的合成及性质研究

Synthesis and properties ofA D-π-A terpyridine derivative and its zinc complex

邓奕 王亚轩 胡磊 王慧
商丘师范学院学报2024,Vol.40Issue(9) :31-35.

D-π-A型三联吡啶衍生物及其锌配合物的合成及性质研究

Synthesis and properties ofA D-π-A terpyridine derivative and its zinc complex

邓奕 1王亚轩 1胡磊 1王慧1
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作者信息

  • 1. 皖南医学院药学院,安徽芜湖 241002
  • 折叠

摘要

以4-正丁氧基苯甲醛为电子给体,三联吡啶为电子受体,通过Witting成烯反应设计并合成了一种D-π-A构型的三联吡啶衍生物DY,并进一步与六水合硝酸锌反应,合成了一种锌(Ⅱ)配合物DY-Zn.通过核磁共振氢谱和红外光谱对化合物DY和DY-Zn的结构进行了表征.利用紫外-可见吸收光谱和荧光光谱研究了二者的光学性质.结果表明,配合物DY-Zn具有良好的聚集诱导荧光增强性质,在含水量为80%时,荧光强度达到最高值,而化合物DY表现出聚集诱导荧光淬灭性质.

Abstract

A D-π-A terpyridine derivative DY was designed and synthesized by Witting reaction using 4-n-butoxy-benzaldehyde as electron donor and terpyridine as electron acceptor.Its zinc(Ⅱ)complex DY-Zn was synthesized by reacting with Zn(NO3)2·6H2O.The structures of DY and DY-Zn were characterized by 1H NMR spectroscopy and infrared spectroscopy.The optical properties of UV-vis absorption spectra and fluorescence emission spectra were studied.The results demonstrated that complex DY-Zn has good aggregation-induced enhanced emission properties,and the fluorescence intensity reaches the highest value when the water content is 80%,while compound DY exhibits an aggregation-induced quenching properties.

关键词

三联吡啶衍生物/锌(Ⅱ)配合物/荧光性质/聚集诱导发光

Key words

terpyridine derivative/zinc(Ⅱ)complex/fluorescence property/aggregation-induced emission property

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基金项目

安徽省自然科学基金青年项目(1908085QB50)

皖南医学院大学生科研资助金项目(WK2022XS11)

出版年

2024
商丘师范学院学报
商丘师范学院

商丘师范学院学报

CHSSCD
影响因子:0.211
ISSN:1672-3600
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