首页|聚丙烯酰胺对水泥砂浆性能影响研究

聚丙烯酰胺对水泥砂浆性能影响研究

Study on the Properties of Cement Mortar Under the Influence of Polyacrylamide

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机制砂是天然河砂替代品,受建筑业广泛关注,然而生产过程引入的聚丙烯酰胺(PAM)对混凝土性能影响较大且研究成果不成体系,限制了机制砂的应用推广.本文选用市面常见十一种PAM,探究不同离子类型、分子量、掺量对水泥砂浆工作性能、力学性能影响.研究表明,PAM掺量对胶砂流动度的干扰明显大于分子量和离子类型,其中阴离子型聚丙烯酰胺(APAM)在0.005%掺量时对水泥胶砂流动度影响较大(-10.7%).PAM令胶砂28天强度略有上升,其中阳离子聚丙烯酰胺(CPAM)对强度提升较大,CPAM 600万0.005%标养28 d强度提升最高为14.3%,APAM 800万0.005%强度提高9.3%.此外,PAM会显著降低聚羧酸高效减水剂(PCE)减水效果,流动度最低降低15%,最高降低28.6%,强度最低降低11.6%,是因为PCE、PAM与水泥颗粒结合时存在竞争关系,PAM会干扰PCE对水泥颗粒的分散作用,抑制该干扰将成为后续探索PAM不利影响的解决方案新思路.另外掺PAM试块的收缩试验数据对水分条件异常敏感,干燥收缩与化学收缩所得结论相反,因此建议选用机制砂作为细骨料的工程养护时需格外注意养护湿度.
Manufactured sand is a substitute for natural river sand and has attracted widespread attention in the construction industry.However,the polyacrylamide(PAM)introduced during the production process has a great impact on the performance of concrete,limiting the promotion and application of manufactured sand in projects.Eleven common PAMs on the market are used to explore the effects of different molecular weights and concentrations on the working performance and mechanical properties of cement mortar.Research shows that the interference of concentration on the fluidity of mortar is significantly greater than the impact of molecular weight and ion type.Among them,anionic polyacrylamide(APAM)degrades the fluidity of mortar the most(-10.7%)at a concentration of 0.005%.In terms of strength,research shows that adding PAM can slightly improve the 28-day strength of mortar.Among them,cationic polyacrylamide(CP AM)has a greater improvement in strength.The 28-day strength improvement at the dosage of CP AM 6 million and 0.005%is the highest by 14.3%,and APAM 8 million.The strength increased by 9.3%at a dosage of 0.005%.In addition,research shows that PAM will significantly reduce the effectiveness of polycarboxylic acid superplasticizer(PCE),with a minimum reduction of 15%in fluidity and a minimum reduction of 11.6%in strength.PCE and PAM have a competitive relationship,and it is necessary to find solutions to the adverse effects of PAM for subsequent scientific research.The program provides new perspectives for thinking.At the same time,the test blocks mixed with PAM are extremely sensitive to moisture conditions in terms of shrinkage.When selecting machine-made sand,special attention must be paid to the maintenance humidity.

ordinary Portland cementpolyacrylamideworking performancemechanical propertiesdrying shrinkage

崔飞、王传林、郑跃群、关嘉琪、陈宏达

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汕头大学工学院土木与环境工程系,广东 汕头 515063

普通硅酸盐水泥 聚丙烯酰胺 工作性能 力学性能 干燥收缩

广东省自然科学基金广东省普通高等学校青年创新人才项目

2023A15150127272021KQNCX021

2024

汕头大学学报(自然科学版)
汕头大学

汕头大学学报(自然科学版)

影响因子:0.391
ISSN:1001-4217
年,卷(期):2024.39(2)
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