首页|分光光度法测定锂云母精矿中三氧化二铁含量的不确定度评定

分光光度法测定锂云母精矿中三氧化二铁含量的不确定度评定

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本文采用邻二氮杂菲分光光度法测定锂云母精矿中三氧化二铁的含量,对结果的不确定度进行评价.采用邻二氮杂菲分光光度法,建立数学模型,分析不确定度来源.各不确定度来源主要为曲线的绘制、三氧化二铁标准溶液浓度、定容体积、移取体积、比色体积、称样试料、重复测量,其中曲线绘制和三氧化二铁标准溶液浓度对不确定度影响较大.本次测定中锂云母精矿中三氧化二铁的含量结果可表示为 0.205 4%±0.011 9%,k=2.
Uncertainty Evaluation of Determination of Iron Oxide Content in Lithium Mica Concentrate by Spectrophotometric Method
This paper adopts the o-phenanthroline spectrophotometric method to measure the content of iron oxide in lithium mica concentrate and evaluates the uncertainty of the results.The o-phenanthroline spectrophotometric method is used to establish a mathematical model and analyze the sources of uncertainty.The main sources of uncertainty are the plotting of the curve,the concentration of the iron oxide standard solution,the volume of the solution,the volume of pipette,the volume of the colorimeter,the weight of the sample,and the repeated measurement.Among these,the plotting of the curve and the concentration the iron oxide standard solution have a greater impact on the uncertainty.The content of iron oxide in lithium mica concentrate in this measurement can be expressed as 0.205 4%±0.011 9%,k=2.

o-phenanthrene spectrophotometric methodlithium mica concentrateiron oxideuncertainty

彭桂香、戴泽桦、章力

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宜春市锂电产业研究院,江西 宜春 336000

江西省科学院应用化学所,江西 南昌 330096

邻二氮杂菲分光光度法 锂云母精矿 三氧化二铁 不确定度

2024

生物化工

生物化工

ISSN:
年,卷(期):2024.10(5)