首页|面向人体健康监测的氮化镓氨气气敏传感器性能分析

面向人体健康监测的氮化镓氨气气敏传感器性能分析

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目的 了解人体呼出气体的疾病标志物,实现人体呼出氨气的实时监测。方法 采用水热法结合高温氮化制备得到多孔氮化镓(GaN)纳米椭球体,将其作为传感器膜涂敷于带有金电极的叉指电极表面,得到NH3的室温快速检测传感器。利用X射线衍射仪、扫描电子显微镜和比表面积测试等对所制备材料的组成和形貌进行了表征,可见合成的GaN是具有大比表面积的多孔纳米结构。测试了传感器对NH3的动态响应、选择性、重复性和稳定性等性能。结果 室温条件下,传感器对100 × 10-6 NH3的响应度(ΔG/G0)约为448%,且表现出快速的响应时间及恢复时间(分别为22 s和24 s)。此传感器对(1~200)× 10-6范围内的NH3具有良好的线性响应,可以实现对NH3的定量检测。GaN气敏传感器对NH3的检出限可达178 × 10-9,可实现对微量NH3的检测。此外,探究了 GaN对NH3响应的传感机制。结论 该研究为面向人体健康监测的NH3传感器研究提供了理论和实验基础。
Performance analysis of NH3 sensor based on GaN for human health monitoring
Objective To understand the disease markers of human exhaled gas and realize the real-time monitoring of hu-man exhaled NH3.Methods The porous GaCl3(GaN)nanoellipsoids were prepared by hydrothermal method and further high temperature nitridation,which were coated on surface of interdigital electrode with gold electrode as sensor film to obtain rapid detection sensor for NH3 at room temperature.The morphology and structure of GaN nanoellipsoids were characterized by X-ray diffraction,scanning electron microscopy and Brunauer-Emmett-Teller method,which showed that the synthesized GaN was porous nanostructure with large specific surface area.The dynamic response,selectivity,repeatability and stability of the sensor to NH3 were tested.Results At room temperature,the sensor responsivity(ΔG/G0)to 100 ×10-6 NH3 was about 448%,and the sensor exhibited fast response time(22-seconds)and recovery time(24-seconds).The GaN nanoellipsoids sensor showed good linear response for NH3 in range of(1-200)×10-6,which was used for quantitative detection of NH3.The detection limit of GaN nanoellipsoids sensor reached 178×10-9,which was used for trace detection of NH3.In addition,the gas sensing mechanism of sensor to NH3 was investigated.Conclusion It is demonstrated that the study provides the theoretical and experimental basis for research of NH3 sensor in human health monitoring.

GaNNH3gas sensorhuman health monitoring

张艺、陈毅、李栋辉、韩丹、王磊

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山西省肿瘤医院,中国医学科学院 肿瘤医院山西医院,山西医科大学附属肿瘤医院,山西 太原 030013

太原理工大学信息与计算机学院/微纳传感与人工智能感知山西省重点实验室,山西太原 030024

氮化镓 氨气 气敏传感器 人体健康检测

山西省重点研发计划

202102030201003

2024

生物医学工程与临床
天津市生物医学工程学会,天津市第三中心医院

生物医学工程与临床

CSTPCD
影响因子:0.462
ISSN:1009-7090
年,卷(期):2024.28(2)
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