首页|原位电化学辅助还原制备石墨烯/银纳米粒子@多金属氧簇复合薄膜及其抗菌性能

原位电化学辅助还原制备石墨烯/银纳米粒子@多金属氧簇复合薄膜及其抗菌性能

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结合层层自组装法和电化学辅助还原法,原位制备了一种还原态氧化石墨烯(rGO)/银纳米粒子(Ag Nps)@多金属氧簇(P2W18)复合薄膜{(PEI/rGO)n-Ag@P2W18},并根据Kirby-Bauer法测试了该复合薄膜对枯草芽孢杆菌和金黄色葡萄球菌的抗菌性能。通过与层层自组装法制备的{PEI/Ag@P2W18}n和{PEI/(rGO-Ag@P2W18)}n薄膜比较发现,仅负载单层抗菌组分Ag@P2W18 的{(PEI/rGO)3-Ag@P2W18}复合薄膜(对枯草芽孢杆菌抑菌环为17。2 mm)抗菌性能高于负载三层Ag@P2W18 的{PEI/Ag@P2W18}3(对枯草芽孢杆菌抑菌环为14。8 mm),与负载三层Ag@P2W18 的{PEI/(rGO-Ag@P2W18)}3薄膜(对枯草芽孢杆菌抑菌环为17。4 mm)抗菌性能相当,说明电化学辅助还原法可以有效提升复合薄膜的抗菌性能。
Assembly of rGO/POM/silver Nanoparticles Films by In-Situ Electrochemical-assisted Reduction:Enhanced Antibacterial Effect
A reduced graphene oxide(rGO)/polyoxometalate(POM)/silver nanoparticles(Ag NPs)composite film{(PEI/rGO)n-Ag@P2W18}fabricated by combining layer self-assembly and in-situ electrochemical-assisted reduction method.The antibacterial effects of{(PEI/rGO)n-Ag@P2W18}composite film for Bacillus subtilis and Glucococcus aureus were investigated by Kirby-Bauer method.Compared with{PEI/Ag@P2W18}n and{PEI/(rGO-Ag@P2W18)}n films prepared by Layer by layer method,the antibacteri-al activity of{(PEI/rGO)3-Ag@P2W18}composite film(17.2 mm for bacteriostatic annulus of Bacillus subtilis)loading monolayer of Ag@P2W18 were higher than the{PEI/Ag@P2W18}3 film(14.8 mm for bacteriostatic annulus of Bacillus subtilis),comparable to the{(PEI/rGO)3-Ag@P2W18}film(17.4 mm for bacteriostatic annulus of Bacillus subtilis)with three layers of Ag@P2W18.The re-sults demonstrated that the antibacterial activity of composite film fabricated by in-situ electrochemical-assisted reduction has been greatly enhanced.

polyoxometalatesgrapheneAg nanoparticlesantibacterial

鲍雅妍、冯锋

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山西大同大学化学与化工学院,山西大同 037009

多金属氧酸盐 石墨烯 银纳米粒子 抗菌

国家自然科学基金资助项目2019年山西大同大学校级科研项目

224761182019K3

2024

山西大同大学学报(自然科学版)
山西大同大学

山西大同大学学报(自然科学版)

影响因子:0.271
ISSN:1674-0874
年,卷(期):2024.40(5)