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硝酸分解磷矿粉生产硝酸钾

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用稀硝酸分解磷矿粉,在100 ℃反应2 h.加入硫酸钾,在100 ℃进行沉钙反应2.5 h.过滤除去硫酸钙,滤液冷却、结晶、过滤、干燥,得硝酸钾产品.实验表明,适宜的工艺条件为:硝酸与磷矿粉的摩尔比20 : 1,硫酸钾与磷矿粉的摩尔比为8 : 1.在此条件下,产品硝酸钾纯度80%~90%,氮钾收率加和值164.32%.
Preparation of potassium nitrate by decomposing phosphorite powder
Phosphorite powders were decomposed by nitric acid for 2 h at 100 ℃.Adding potassium sulfate to the complex,then calcium was precipitated for (2.5 h) at 100 ℃.Calcium sulfate was filtrated and removed.Potassium nitrate was obtained by cooling,crystallization and drying of filtrate.The experimental results showed that when the molar ratio of nitric acid to phosphorite powder is 20:1,and the molar ratio of potassium sulfate to phosphorite powder is 8 : 1,the purity of potassium nitrate is 80%~90% and the total yield of nitrogen and potassium is 164.32%.

potassium nitratephosphorite powdernitric acidpotassium sulfate

马凯、马培华、武四海、贲艳英

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中国-阿拉伯化肥有限公司,河北,秦皇岛,066000

硝酸钾 磷矿粉 硝酸 硫酸钾

2010

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCDCSCD
影响因子:0.411
ISSN:1671-3206
年,卷(期):2010.39(2)
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