首页|f-CTBN/PEG聚氨酯材料的合成及性能研究

f-CTBN/PEG聚氨酯材料的合成及性能研究

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以三乙醇胺得到的功能化丁腈橡胶(f-CTBN)和不同相对分子质量聚乙二醇(PEG)为基本物质,逐步聚合得到一系列高支化嵌段聚氨酯材料.探究f-CTBN、PEG的用量和固化剂(HDI与H12MDI)的不同对材料性能的影响,通过形貌观察、力学性能测试、毒性试验来综合评价,发现物料比m(f-CTBN)/m(PEG)为3∶7聚氨酯有望成为医用薄膜.
Synthesis and properties of f-CTBN/PEG polyurethane materials
A series of novel highly-branched polyurethanes (PUR) were established and polymerized on the basis of the triethanolamine-hyperbranched carboxyl-terminated poly ( butadiene-co-acrylonitrile) (/-CTBN) and poly ( ethylene glycol) (PEG) with step-by-step synthetical method. The material properties of amount of /-CTBN and PEG and curing agent (HDI and H12MDI). Micrograph, mechanical properties and toxicity test used to evaluate. Those results showed PUR at the m(f-CTBN)/m(PEG) 3:7 will have been becoming medical film products in the biomedical field.

hyperbranched polyurethanessynthesistoxicity

张常虎

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西安文理学院化学与化学工程学院,陕西西安710065

高支化聚氨酯 合成 毒性

陕西省分析化学重点学科基金西安文理学院中青年科研基金

3811kyc201014

2012

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCDCSCD
影响因子:0.411
ISSN:1671-3206
年,卷(期):2012.41(9)
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