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催化裂解法处理多晶硅行业中的氯硅烷高沸物

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使用有机胺类催化剂催化裂解多晶硅生产过程中副产的氯硅烷高沸物,考察了反应温度以及催化剂种类对高沸物催化裂解反应的影响并对反应机理进行了分析。结果表明,以N,N-二甲基苯胺为催化剂,反应温度 130~135℃,反应时间1。5 h,催化剂用量8%时,单硅烷产物的收率可达79。99%。
Catalytic cracking of high-boiling chlorosilane in the polysilicon industry
The harmless treatment and resource utilization of the high boiling chlorosilane produced by products in the process of polycrystalline silicon production can be realized by using organic amine cata-lyst.The effects of reaction temperature and catalyst type on the catalytic cracking of high-boiling chlorosi-lane was investigated and the reaction mechanism was analyzed.The results showed that,using N,N-dime-thylbenzylamine as the catalyst,at a reaction temperature of 130~135℃,a reaction time of 1.5 h,and a catalyst amount of 8%,the yield of monosilane product could reach 79.99%.

high-boiling chlorosilanecatalytic cleavage reactionorganic aminewaste disposalpoly-crystalline silicon

王金可、马跃、岳长涛

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中国石油大学(北京)理学院 能源交叉学科基础研究中心,北京 102249

氯硅烷高沸物 催化裂解 有机胺 废物处理 多晶硅

国家重点研发计划

2019YFC1907601

2024

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
年,卷(期):2024.53(1)
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