首页|鲜胶乳熟化时间对天然橡胶组成及性能的影响

鲜胶乳熟化时间对天然橡胶组成及性能的影响

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采用复合保存剂HY/NH3 保存鲜胶乳1~5d,定期取样凝固制备成天然生胶,以胶乳熟化时间为1d的样品作对照样,探究鲜胶乳熟化时间对天然橡胶组成、性能的影响。分别采用红外光谱仪、核磁共振交联密度仪、拉力试验机等仪器对天然橡胶进行表征。结果表明,鲜胶乳熟化可以减少天然生胶中杂质、灰分、挥发物的含量,提高塑性保持率及交联密度;混炼胶的焦烧时间、正硫化时间、扭矩差值以及硫化胶的拉伸强度、撕裂强度、定伸应力等均有提高;胶乳熟化3d制备的天然橡胶综合性能最好,其硫化胶的拉伸强度、撕裂强度分别达到 20。47 MPa、30。38 kN/m,比对照样提高了3。5%和7。0%。
Effects of latex maturation time on composition and properties of natural rubber
The fresh latex was preserved using the composite preservative HY/NH3 for 1~5 d,regular sampling and solidification to prepare raw rubber.A sample with a latex maturation time of 1 d was used as a control sample to investigate the effect of maturation time of fresh latex on the composition and prop-erties of natural rubber.The natural rubber was characterised using instruments such as infrared spectros-copy,nuclear magnetic resonance crosslink density and tensile testing machines,respectively.The results showed that the maturation of fresh latex could reduce the content of impurities,ash and volatiles in raw rubber sheets,and improve the plasticity retention index and cross-link density.The scorch time,positive vulcanization time,torque difference of compounded rubber and tensile strength,tear strength,constant tensile stress of vulcanized rubber were all improved.The natural rubber prepared from the fresh latex for 3 d of maturation had the best overall performance,and the tensile strength and tear strength of vulcanized rubber reached were up to 20.47 MPa and 30.38 kN/m,respectively,an increase of 3.5%and 7.0%compared to the control sample.

natural rubberlatex maturationnon-rubber componentsphysical and mechanical properties

李建伟、黄红海、李云、丁丽、戴拓、赵立广、吴凡、桂红星

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中国热带农业科学院橡胶研究所,海南 海口 571101

海南省天然橡胶栽培与加工工程研究中心,海南 海口 571101

勐腊田野橡胶销售有限责任公司,云南 西双版纳 666303

天然橡胶 胶乳熟化 非胶组分 物理机械性能

国家重点研发部省联动计划项目国家天然橡胶产业技术体系建设专项

2022YFD2301203CARS-33-JG1

2024

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
年,卷(期):2024.53(1)
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