应用化工2024,Vol.53Issue(1) :97-101.

焦炭-水蒸气催化气化反应特性研究

Reaction characteristic of the coke catalytic gasification with steam

唐瑞源 梁馨文 张玉玉 张君涛 罗建玲 姚晓莎
应用化工2024,Vol.53Issue(1) :97-101.

焦炭-水蒸气催化气化反应特性研究

Reaction characteristic of the coke catalytic gasification with steam

唐瑞源 1梁馨文 1张玉玉 1张君涛 1罗建玲 1姚晓莎1
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作者信息

  • 1. 西安石油大学 西安市高碳资源低碳化利用重点实验室,陕西 西安 710065
  • 折叠

摘要

采用碱性待生剂为气化原料,考察焦炭与水蒸气催化气化反应特性.在消除内外扩散影响的前提下,探讨了气化反应温度、进水蒸汽、混合气体比例及气化时间对焦炭水蒸气催化气化反应的影响.结果表明,碱性待生剂上焦炭催化气化反应速率与气化反应温度成正比,进水蒸汽速率为2.5 L/min时,可基本消除水蒸气的扩散效应对焦炭催化气化反应的影响,碱性待生剂上焦炭转化率基本趋于稳定,气化反应时间30 min,可较好转化碱性待生剂上焦炭,产品气以H2 组成为主(含量约60%).水蒸气/氧气混合气为气化剂可显著提高焦炭催化气化转化率,同时,氧气的加入会影响合成气组成.合成气中H2 和CO含量降低,CO2 含量升高.

Abstract

The catalytic gasification of coke with steam was studied by using spent base catalysts as gasifi-cation raw material.On the premise of eliminating the influence of internal and external diffusion,the per-formance of gasification temperature,influent steam,gas mixture ratios and gasification time on the catalyt-ic gasification of coke steam were discussed.The results show that the reaction rate of coke catalytic gasi-fication on the base catalyst is proportional to gasification reaction temperature,and the effect of water va-por diffusion on the coke catalytic gasification can be basically eliminated,when the rate of inlet steam is 2.5 L/min.The conversion rate of coke on the alkaline reagent tends to be stable basically.The gasifica-tion reaction time is at least 30 min to achieve a better conversion of coke on the base spent catalyst.The product gasismainly composed of H2(approximately60%).Steam/oxygen gasification reagent isused in the gasification reaction,which could obviously improve the conversion rate of the coke,and meanwhile af-fect the composition of synthesis gas.The content of H2 and CO in syngas decreased,while the content of CO2 increased.

关键词

焦炭/水蒸气/碱性待生剂/催化气化

Key words

coke/steam/spent catalyst/catalytic gasification

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基金项目

陕西省教育厅科研计划项目(21JK0842)

陕西省自然科学基础研究计划(2021JQ-583)

西安石油大学研究生创新与实践能力培养项目(YCS22214213)

大学生创新创业项目(S202120705056)

出版年

2024
应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
参考文献量5
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