首页|烷基糖苷和醇醚糖苷对辽河稠油的界面张力的影响研究

烷基糖苷和醇醚糖苷对辽河稠油的界面张力的影响研究

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利用旋转滴界面张力仪,研究了在增加环氧乙烷基团(EO)的情况下,烷基糖苷与醇醚糖苷单独使用对正构烷烃及辽河原油之间的界面张力的影响、在复合体系下对界面张力的影响;考察了表面活性剂质量分数、一价与二价离子浓度和EO基团对体系动态界面张力的影响。结果表明,两种糖苷型表面活性剂可以与十二烷基苯磺酸钠产生较强的协同作用,同时EO链可以调节表面活性剂的亲水亲油平衡值,使得表面活性剂在界面处排列更紧密;矿化度的增加可以压缩双电子层,使得界面处分子紧密排布,降低界面张力。在适当的矿化度条件下,复配表面活性剂系统可以与辽河稠油间产生超低界面张力。
Effect of alkyl glycosides and alcohol ether glycosides on interfacial tension of Liaohe viscous oil
The effects of alkyl glycoside and alcohol ether glycoside alone on the interfacial tension be-tween n-alkanes and Liaohe crude oil and on the interfacial tension in a composite system were studied by using a rotary drop interfacial tensimeter with the addition of ethylene oxide group(EO).The effects of mass fraction of surfactant,concentration of univalent and bivalent ions and EO group on dynamic interfa-cial tension of the system were investigated.The results show that the two glycoside surfactants can pro-duce strong synergistic effect with sodium dodecylbenzene sulfonate,and the EO chain can adjust the hy-drophilic and oleophilic balance of the surfactants,so that the surfactants are more closely arranged at the interface.The increase of salinity can compress the double electron layer,make the interfacial molecules closely arranged,and reduce the interfacial tension.Under proper salinity conditions,the mixed surfactant system can produce ultra-low interfacial tension with Liaohe viscous oil.

interfacial tensionviscous oilmineralizationsurfactantsn-alkanes

刘俊鹏、吴玉国

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辽宁石油化工大学 石油天然气工程学院,辽宁 抚顺 113001

界面张力 稠油 矿化度 表面活性剂 正构烷烃

辽宁省博士科研启动基金计划项目辽宁省教育厅科学研究项目辽宁省高等学校创新人才支持计划项目

2020-BS-227L20200242020-68

2024

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
年,卷(期):2024.53(1)
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