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甲基丙烯酸长碳链酯的合成及应用研究进展

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概述了甲基丙烯酸长碳链酯的合成方法及反应机理,重点介绍了传统磺酸类、离子交换型树脂、固体酸、碱金属类、金属负载型、离子液体等催化剂合成甲基丙烯酸长碳链酯的研究进展,并梳理了每种催化剂在应用过程中的特点,综述了国内外关于甲基丙烯酸长碳链酯在材料、纺织、涂料等应用领域的研究进展.由于甲基丙烯酸长碳链酯的酯化产量不高,应用领域也比较有限,未来应继续开发合成甲基丙烯酸长碳链酯的绿色、环保催化剂体系,扩大其在不同应用领域的研究.
Research progress on the synthesis and application of long carbon chain methacrylates
The synthesis methods and reaction mechanisms of long carbon chain methacrylates are summa-rized,and the research progress of traditional sulfonic acid,ion-exchange resin,solid acid,alkali metal,metal-loaded,ionic liquid and other catalysts for the synthesis of long carbon chain methacrylates are highlighted,and the characteristics of each catalyst in the application process are sorted out.The progres-ses of domestic and international research on long carbon chain methacrylates in materials,textiles,coating and other applications are reviewed.Since the esterification yield of long carbon chain methacrylates is not high and the application fields are relatively limited,we should continue to develop green and environmen-tally friendly catalyst systems for the synthesis of long carbon chain methacrylates and expand their re-search in different application fields in the future.

long carbon chain methacrylatessynthesiscatalystapplication

赵小艳、房成、吴超波

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南京林业大学 化学工程学院,江苏 南京 210037

甲基丙烯酸长碳链酯 合成 催化剂 应用

国家重点研发计划江苏省双创计划江苏省博士后科研资助计划

2018YFD0600405苏人才办[2019]20号2019K141

2024

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
年,卷(期):2024.53(1)
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