首页|催化氧化法脱除甲苯研究进展

催化氧化法脱除甲苯研究进展

扫码查看
将催化氧化法分为热催化、光催化、电催化和PMS活化催化4 类,总结其在脱除甲苯方面的应用,发现近年来如Pt、Au、Ag、CeO2 等贵金属及金属氧化物在催化剂中的应用越来越广泛,其在不同材料表面的负载能够显著影响其催化剂成品的强度、孔隙率等物理性质,进而影响其对工况的适应范围和经济效益.详细分析了催化材料和反应条件对脱除甲苯效率的影响,阐明了不同类型脱除甲苯反应的本质.根据各个类型的反应温度和研究时间指出催化氧化法必然向着反应条件更加温和的方向发展,且有自由基参与的催化氧化方法因其节能且高效的特质,必然会受到更多关注与应用.最后,指出了当前研究难以应用于工程且反应机理探究不足的问题,并提出了发展建议.
Research progress in toluene removal by advanced oxidation
The catalytic oxidation methods are divided into four categories:thermal catalysis,photocataly-sis,electrocatalysis and PMS activated catalysis,and their applications in the removal of toluene are sum-marized.It is found that the application of precious metals and metal oxides such as Pt,Au,Ag and CeO2 in catalysts has become more and more extensive in recent years.The load on the surface of different ma-terials can significantly affect the physical properties of the finished catalyst such as strength and porosity,and then affect its adaptability to the working conditions and economic benefits.Then,the effects of cata-lytic materials and reaction conditions on the efficiency of toluene removal were analyzed in detail,and the nature of different types of toluene removal reactions was explained.In addition,according to the different types of reaction temperatures and research time,it is pointed out that catalytic oxidation methods are bound to develop in the direction of more moderate reaction conditions,and catalytic oxidation methods in-volving free radicals are bound to receive more attention and application because of their energy-saving and efficient characteristics.Finally,it is pointed out that the current research is difficult to apply to engi-neering and the research of reaction mechanism is insufficient,and the development suggestions are put forward.

advanced oxidation methodfree radicalscatalysistoluene removal

毛俞敏、宋云畅、郝润龙

展开 >

华北电力大学 环境科学与工程系 燃煤电站烟气多污染物协同控制河北省重点实验室,河北 保定 071003

高级氧化法 自由基 催化 脱除甲苯

国家自然科学基金青年项目

52000067

2024

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
年,卷(期):2024.53(1)
  • 1