首页|缺陷型Cu-Bi共掺杂TiO2光催化剂的制备及其降解四环素的研究

缺陷型Cu-Bi共掺杂TiO2光催化剂的制备及其降解四环素的研究

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以钛酸四丁酯、硝酸铜、硝酸铋为原料,采用溶胶-凝胶法制备前驱体溶液,经干燥、机械活化(MA)、煅烧处理,制备缺陷型Cu-Bi共掺杂TiO2复合光催化剂,利用XRD、SEM、TEM、XPS、BET、PL等进行表征,在可见光辐照下,对光催化剂降解的盐酸四环素(TC)性能进行了研究.结果表明,在MA处理20 min,铜、铋掺杂量均为1%,用量0.25 g/L的条件下,120 min内TC降解率达96.5%.
Preparation of defective Cu-Bi co-doped TiO2 composite photocatalyst and its degradation of tetracycline
The precursor solution was prepared by sol-gel method using tetrabutyl titanate,copper nitrate and bismuth nitrate as raw materials.The defective Cu-Bi co-doped TiO2 composite photocatalyst was suc-cessfully prepared through drying,mechanical activation(MA)and calcination,the defective Cu-Bi co-doped TiO2 composite photocatalyst was characterized by XRD,SEM,TEM,XPS,BET,and PL,and tetra-cycline hydrochloride(TC)was researched to perform photocatalytic degradation under visible light irradi-ation.The results showed that 96.5%of TC could be degraded within 120 min under the condition of 1%copper-bismuth doping with dosage of 0.25 g/L after 20 min MA treatment.

titanium dioxidedefective engineeringmechanical activationtetracycline hydrochloridepho-tocatalysis

周南、张燕娟、黄祖强、甘涛、胡华宇

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广西大学化学化工学院,广西南宁 530004

二氧化钛 缺陷工程 机械活化 盐酸四环素 光催化

国家自然科学基金资助项目国家自然科学基金资助项目广西自然科学基金项目广西自然科学基金项目

22068007221780742022GXNSFBA0354792019GXNSFDA245020

2024

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
年,卷(期):2024.53(2)
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