首页|双改性活性氧化铝除氟吸附性能研究

双改性活性氧化铝除氟吸附性能研究

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为进一步提高活性氧化铝的吸附性能,设计了一种先酸化再化学浸渍的改性方法,分别制备两种吸附剂:载镧/镁硝酸酸化活性氧化铝(LHAA/MHAA)。研究了 LHAA与MHAA的吸附性能,探讨了除氟机理。结果表明,吸附时间2 h,投加量2 g/L,pH=6,振荡频率180 r/min,对20 mg/L的含氟水最佳去除率分别为93%与90%,最大吸附容量为17。64 mg/g与10。96 mg/g,两者对氟离子的吸附等温线均符合Langmuir等温线模型,吸附动力学拟合均符合伪二级动力学。
Study on defluorination adsorption performance of double modified activated alumina
In order to further improve the adsorption performance of activated alumina,two kinds of adsor-bents,nitrate acidified activated alumina loaded lanthanum(LHAA)and loaded magnesium(MHAA),were prepared with the combination of nitrate acidification and chemical impregnation.The adsorption per-formance of LHAA and MHAA was studied,and the mechanism of fluoride removal was explored.The re-sults showed that the optimal removal rate of 20 mg/L fluoride water were 93%and 90%respectively,and the maximum adsorption capacities were 17.64 mg/g and 10.96 mg/g,respectively,when the adsorp-tion time was 2 h,the dosage was 2 g/L,pH=6,and the oscillation frequency was 180 r/min.The adsorp-tion isotherms of fluoride ions by both of them conformed to the Langmuir isotherm model,and the adsorp-tion kinetics fitting conformed to the pseudo second order kinetics.

modified activated aluminachemical impregnationacidificationadsorption isothermad-sorption kineticsdefluorination

阎晗、刘海燕、刘洋虹、殷耀兵

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河北工程大学能源与环境工程学院,河北邯郸 056038

河北工程大学材料科学与工程学院,河北邯郸 056038

活性氧化铝 化学浸渍 酸化 吸附等温线 吸附动力学 除氟

河北省重大科技成果转化项目河北省科技计划

21281203Z17274008D

2024

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
年,卷(期):2024.53(2)
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