应用化工2024,Vol.53Issue(2) :354-357.

双改性活性氧化铝除氟吸附性能研究

Study on defluorination adsorption performance of double modified activated alumina

阎晗 刘海燕 刘洋虹 殷耀兵
应用化工2024,Vol.53Issue(2) :354-357.

双改性活性氧化铝除氟吸附性能研究

Study on defluorination adsorption performance of double modified activated alumina

阎晗 1刘海燕 1刘洋虹 1殷耀兵2
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作者信息

  • 1. 河北工程大学能源与环境工程学院,河北邯郸 056038
  • 2. 河北工程大学材料科学与工程学院,河北邯郸 056038
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摘要

为进一步提高活性氧化铝的吸附性能,设计了一种先酸化再化学浸渍的改性方法,分别制备两种吸附剂:载镧/镁硝酸酸化活性氧化铝(LHAA/MHAA).研究了 LHAA与MHAA的吸附性能,探讨了除氟机理.结果表明,吸附时间2 h,投加量2 g/L,pH=6,振荡频率180 r/min,对20 mg/L的含氟水最佳去除率分别为93%与90%,最大吸附容量为17.64 mg/g与10.96 mg/g,两者对氟离子的吸附等温线均符合Langmuir等温线模型,吸附动力学拟合均符合伪二级动力学.

Abstract

In order to further improve the adsorption performance of activated alumina,two kinds of adsor-bents,nitrate acidified activated alumina loaded lanthanum(LHAA)and loaded magnesium(MHAA),were prepared with the combination of nitrate acidification and chemical impregnation.The adsorption per-formance of LHAA and MHAA was studied,and the mechanism of fluoride removal was explored.The re-sults showed that the optimal removal rate of 20 mg/L fluoride water were 93%and 90%respectively,and the maximum adsorption capacities were 17.64 mg/g and 10.96 mg/g,respectively,when the adsorp-tion time was 2 h,the dosage was 2 g/L,pH=6,and the oscillation frequency was 180 r/min.The adsorp-tion isotherms of fluoride ions by both of them conformed to the Langmuir isotherm model,and the adsorp-tion kinetics fitting conformed to the pseudo second order kinetics.

关键词

活性氧化铝/化学浸渍/酸化/吸附等温线/吸附动力学/除氟

Key words

modified activated alumina/chemical impregnation/acidification/adsorption isotherm/ad-sorption kinetics/defluorination

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基金项目

河北省重大科技成果转化项目(21281203Z)

河北省科技计划(17274008D)

出版年

2024
应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
参考文献量13
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