Application of metal halide coordination polymer in photocatalysis
This paper first describes the key problems that limit the development of metal-halide coordina-tion polymer(XCP)materials,such as poor thermal stability,moisture resistance,heavy metal exudation and so on.Then it is mentioned that the halogen coordination atom is introduced into the traditional coor-dination polymer.This strategy can not only effectively improve the light absorption capacity of the materi-al,but also stabilize the excited electrons,which is of great significance to enhance the photocatalytic per-formance of the material.This paper further reviews the research on the photocatalytic degradation of or-ganic pollutants,selective organic synthesis,hydrogen production from water cracking and CO2 reduction of halogenated metal coordination polymer materials,and prospects the application of such materials in the field of photocatalysis.In order to construct long-term stable XCP to achieve efficient photocatalysis,to provide theoretical reference for expanding the application scale and exploring the structure-activity rela-tionship between structure and performance.
万方数据
维普
