应用化工2024,Vol.53Issue(2) :424-427,437.

糠醛MPV还原制糠醇中固体酸碱催化剂的研究进展

Advances in solid acid-base catalysts in the production of furfural alcohol from furfural through MPV reduction

杨荣何 李伏坤 杜子婷 代金杭 曹卿雅 杨德龙
应用化工2024,Vol.53Issue(2) :424-427,437.

糠醛MPV还原制糠醇中固体酸碱催化剂的研究进展

Advances in solid acid-base catalysts in the production of furfural alcohol from furfural through MPV reduction

杨荣何 1李伏坤 1杜子婷 1代金杭 1曹卿雅 1杨德龙1
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作者信息

  • 1. 重庆工商大学环境与资源学院催化与环境新材料重庆市重点实验室,重庆 400067
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摘要

介绍了固体酸碱催化剂在糠醛Meerwein-Ponndorf-Verley(MPV)还原制糠醇中的研究进展.糠醛作为高度商品化的生物基平台化合物,其可通过加氢还原为更具有经济价值的化学品.MPV还原因其条件温和、安全和环保而受到生物炼制领域青睐.介绍MPV典型反应及六元环过渡态的形成过程;对不同固体酸碱催化剂在糠醛MPV还原制糠醇中的研究进展进行总结,其中锆/铪基催化剂具有优异的MPV还原性能被广泛研究;针对固体酸碱催化剂在该领域进行总结,并指出存在的主要问题和解决方法,同时对该领域未来的发展进行展望.

Abstract

The research progress of solid acid-base catalysts in the reduction of furfural Meerwein-Ponndorf-Verley(MPV)to furfuryl alcohol was reviewed.As a highly commercialized biological platform compound,furfural can be reduced into more economical chemicals by hydrogenation.MPV reduction is favored in the field of bio-refining because of its mild conditions,safety and environmental protection.The typical reactions of MPV and the formation of six-membered ring transition states are introduced,and the research progress of different solid acid-base catalysts in the reduction of furfural to furfuryl alcohol with MPV is summarized,the excellent MPV reduction performance of zirconium/hafnium-based catalysts has been widely studied.A summary of solid acid-base catalysts in this field and the main problems and solu-tions in this field are pointed out,at the same time,the future development of this field is prospected.

关键词

固体酸碱催化剂/糠醛/糠醇/MPV还原

Key words

solid acid-base catalysts/furfural/furfuryl alcohol/MPV reduction

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基金项目

国家自然科学基金(21808021)

中国博士后科学基金(2020M673151)

出版年

2024
应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
参考文献量36
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