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外场协同结构调控光催化体系的研究进展

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综述了结构调控增强光催化和外场协同结构调控增强光催化的机理及其最新研究进展,并对各外场增强光催化的优缺点进行了讨论。光催化是一种将太阳能直接转化为化学能的技术,在环境治理和能源危机解决方面具有巨大潜力。光生电子-空穴对的快速复合极大地限制了光催化剂的光催化效率。通过结构调控,如元素掺杂、贵金属负载、构建异质结结构等,可以大大提高光催化效率,但其应用仍有很强的局限性。近年来,外场(机械应力、微波、温度梯度、电场、磁场等)在光催化反应中的应用,显著提高了光催化效率,拓宽了光催化的应用范围。展望了外场协同结构调控增强光催化技术的发展前景和面临的挑战。
Research progress in external fields synergistic structural regulation photocatalytic systems
This article reviews the mechanisms and latest research progress of structural regulation en-hanced photocatalysis and enhanced photocatalysis through external fields synergistic structural regula-tion,and the advantages and disadvantages of each external field enhanced photocatalysis are discussed.Photocatalysis is a technique that converts solar energy directly into chemical energy.It has great potential in environmental governance and energy crisis resolution.The rapid recombination of photoelectron-hole pairs greatly limits the photocatalytic efficiency of photocatalysts.Through structural regulation,such as el-ement doping,noble metal loading,construction of heterojunction structure,can greatly improve the effi-ciency of photocatalysis,but their application still has strong limitations.In recent years,the application of external fields(mechanical stress,microwave,temperature gradient,electric field,magnetic field,etc.)in photocatalytic reactions has significantly improved the efficiency of photocatalysis and broadened the ap-plication range of photocatalysis.The prospects and challenges of enhanced photocatalysis through external fields synergistic structural regulation are discussed.

photocatalysisexternal-fieldcharge separationsemiconductor materialsplasmon

曾昆林、刘一丁

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西南石油大学 化学化工学院,四川 成都 610500

油气田应用化学四川省重点实验室,四川 成都 610500

光催化 外场 电荷分离 半导体材料 等离子激元

四川省创新人才项目油气田应用化学四川省重点实验室开放基金

2023JDRC0006YQKF202202

2024

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
年,卷(期):2024.53(3)
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