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废弃水厂用煤质颗粒活性炭吸附苯甲酸钠性能研究

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直接再利用某水厂的废弃活性炭作为苯甲酸钠的吸附剂。通过对废弃活性炭进行灰分、SEM-BET表征分析得,废弃活性炭表面变得光滑,碘值仅有339。86 mg/g,介孔占比大,表明活性炭表面吸附位点被占据,其吸附性能下降。拟合结果显示,废弃活性炭对苯甲酸钠的吸附更符合Freundlich等温模型和拟二级动力学模型。随着温度的升高,苯甲酸钠的去除率下降,与热力学参数焓变是负值一致,属于放热反应。拟合的废弃活性炭对苯甲酸钠的最大吸附容量为1。108 mg/g,证明了废弃活性炭可应用于工业废水中,为水厂最终处置废弃活性炭找到了新的出路。
Study on the adsorption performance of sodium benzoate on waste coal granular activated carbon from water plants
Waste activated carbon from a water plant is used as the adsorbent of sodium benzoate.Through ash,SEM and BET characterization analysis of the waste activated carbon,the surface of the waste activa-ted carbon became smooth,the iodine value was only 339.86 mg/g,and the mesoporous proportion was large,indicating that the adsorption site on the surface of the activated carbon was occupied,and its ad-sorption performance decreased.The fitting results showed that the adsorption of sodium benzoate by waste activated carbon was more consistent with Freundlich isothermal model and pseudo-second-order kinetic model.With the increase of temperature,the removal rate of sodium benzoate decreases,which is consist-ent with the negative enthalpy change of thermodynamic parameter,and belongs to exothermic reaction.The maximum adsorption capacity of waste activated carbon for sodium benzoate is 1.108 mg/g,which proves that waste activated carbon can be applied to industrial wastewater,and finds a new way for the fi-nal disposal of waste activated carbon in water plants.

disused activated carbonsodium benzoateadsorptionresource utilization

李璐、周克梅、周卫东、范佩、刘振东、周冰洁、吴彬彬、王郑

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南京林业大学 土木工程学院,江苏 南京 210037

南京水务集团有限公司,江苏 南京 210002

废弃活性炭 苯甲酸钠 吸附 资源化利用

国家重点研发计划国家重点研发计划南京水务集团有限公司科技创新项目

2018YFC04080002018YFC0408004YF2022-003

2024

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
年,卷(期):2024.53(4)
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