首页|月桂酰胺硼酸酯水基润滑剂的合成及摩擦学性能研究

月桂酰胺硼酸酯水基润滑剂的合成及摩擦学性能研究

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通过酯化反应和酰胺化反应,在月桂酸的基础上引入B、N极压吸附基团,合成了月桂酰胺硼酸酯液压支架传动介质用润滑剂,利用红外光谱和核磁氢谱进行结构表征,利用四球法考察了添加剂水溶液的摩擦学性能,并探究了润滑机理。结果表明:添加剂具有良好的水解安定性,当质量浓度为0。4%时,PB 值为696 N,磨斑直径随浓度升高逐渐减小后趋于平缓,随载荷升高先增大后减小再增大,这是由于在低载荷下主要靠吸附起到边界润滑作用,随着载荷的增加,摩擦副接触区生成了Fe2 O3、Fe2 B、BN、B2 O3 等物质堆积到金属表面形成的高强度化学反应膜和吸附膜共同形成了复合膜,对摩擦副起到了有效的保护作用。
Synthesis and tribological properties of lauramide borate ester water-based lubricant
Through esterification reaction and amidation reaction,N and B extreme pressure adsorption groups were introduced on the basis of lauric acid to synthesize lauric acid amide borate ester lubricant for hydraulic support transmission medium.The structure was characterized by IR and 1 H NMR.The tribolog-ical properties of additive aqueous solution were investigated by four ball method,and its lubrication mechanism was explored.The results show that the additive has good hydrolytic stability.When the mass concentration is 0.4%,the PB value is 696 N.The wear scar diameter decreases gradually with the in-crease of concentration and then tends to be flat.With the increase of load,the wear scar diameter first in-creases,then decreases and then increases.This is because the boundary lubrication is mainly played by adsorption under low load.With the increase of load,Fe2 O3,Fe2 B,BN,B2 O3 and other substances are formed in the contact area of the friction pair,which are stacked on the metal surface to form a high-strength chemical reaction film and an adsorption film together to form a composite film,which plays an effective role in protecting the friction pair.

water-based lubricantnitrogen-containing boratelubrication mechanismhydrolytic stabili-ty

杭智军、孟征

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煤炭科学技术研究院有限公司 矿用材料分院,北京 100013

煤炭科学研究总院,北京 100013

水基润滑剂 含氮硼酸酯 润滑机理 水解安定性

国家重点研发计划天地科技股份有限公司科技创新创业资金专项

2017YFC06028032022-2-TD-QN004

2024

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
年,卷(期):2024.53(4)
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