首页|氧化石墨烯改性聚偏氟乙烯分离膜的制备、性能及应用

氧化石墨烯改性聚偏氟乙烯分离膜的制备、性能及应用

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简述了聚偏氟乙烯(PVDF)膜与氧化石墨烯(GO)的结构特征,分析了有机-无机杂化膜的优势。详述目前GO/PVDF膜的几种主要制备方法,包括溶液浇铸法、静电纺丝法、化学接枝法、真空抽滤法等,分析了各制备方法的优劣。阐述了GO对PVDF复合膜孔径、亲疏水性能、膜通量、截留性能、力学性能等的影响,并对复合膜在水处理及其他潜在应用进行了综述。分析发现,溶液浇铸法工艺简单、制膜周期短,化学接枝法制得的膜各组分间结合稳固、服役时间长,而静电纺丝法制得的膜比表面积大、孔隙率高。在微观层面,GO片层发生毛细作用、低于片层直径的粒子能以更快的速度通过,宏观上表现为膜通量的提高,GO还能提高膜表面光洁度、减少杂质淤堵与污染,进而提高膜的使用寿命。对GO/PVDF复合膜的发展趋势进行了展望,以期为构建高效稳定的PVDF基分离膜提供理论依据与技术支持。
Preparation,performance and application of polyvinylidene fluoride separation membrane modified by GO
The structure characteristic of polyvinylidene fluoride membrane and graphene oxide was main introduced,respectively,and the advantages of organic-inorganic hybrid membrane were analyzed.The preparation method of GO/PVDF membrane were stated in detail,including solution casting method,elec-trospinning method,chemical grafting method,vacuum filtration method and so on.Based on the recent re-search status,the advantages and disadvantages of the above methods were analyzed.Then,the effects of GO on pore size,hydrophilicity and hydrophobicity,membrane flux,rejection,and mechanical properties of membrane were expounded.And the applications of GO/PVDF membrane in water treatment and other potential applications were reviewed.It was found that the solution casting method was simple and short,and the membrane produced by the chemical grafting method had a stable bond between each component and a long service time,while the membrane produced by the electrostatic spinning method had a large specific surface area and high porosity.The capillary action of the GO lamellar capillarity occurred,and the smaller particles would pass through the GO lamellar at a faster speed,the membrane flux was im-proved in macroscopic view.GO also improved surface finish,reduced the impurities blockage and pollu-tion,and then improving service life of GO/PVDF membrane.The research direction and development trend of GO/PVDF membrane was prospected,thus would provide theoretical basis and technical support for the construction of efficient and stable PVDF separation membrane.

graphene oxidepolyvinylidene fluoridemembrane manufacturewater treatmentsepara-tion membrane

王成达、朱世东、赵乾臻、王国强

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陕西延长石油(集团)有限责任公司研究院 陕西省二氧化碳封存与提高采收率重点实验室,陕西 西安 710065

西安石油大学 材料科学与工程学院,陕西 西安 710065

陕西速源节能科技有限公司,陕西 西安 710077

氧化石墨烯 聚偏氟乙烯 膜制备 水处理 分离膜

国家自然科学基金陕西省重点研发计划

519742452020GY-128

2024

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
年,卷(期):2024.53(4)
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