首页|木屑基介孔活性炭的制备及其对刚果红的高效吸附

木屑基介孔活性炭的制备及其对刚果红的高效吸附

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以废弃生物质木屑作为原料,K2C2O4为活化剂,鸡蛋壳为模板剂制备介孔活性炭.采用扫描电镜(SEM)、X射线光电子能谱仪(XPS)和N2吸附-脱附等温线等方法对活性炭的结构进行表征,并考察了活性炭对刚果红(CR)染料的吸附性能.结果表明,当木屑与K2C2O4的质量比为1∶1.5,添加与木屑等量的鸡蛋壳,活化温度为800℃、活化时间为2 h时,所制备的活性炭AC-1比表面积为2009 m2/g,介孔率可达70.5%.AC-1对CR的最佳吸附容量高达862.1 mg/g.吸附过程是以化学吸附为主的单层复合吸附过程,符合准二级动力学模型和Langmuir等温模型.
Preparation of wood chip based mesoporous activated carbon and its efficient adsorption of Congo red
Using waste biomass sawdust as raw material,K2C2O4 as activator and egg shell as template,mesoporous activated carbon was prepared.The structure of activated carbon was characterized by scan-ning electron microscope(SEM),X-ray photoelectron spectroscopy(XPS)and N2 adsorption-desorption experiments,and the adsorption performance of activated carbon for Congo red dye was investigated.The results show that when the mass ratio of sawdust to K2C2O4 is 1∶1.5,add an equal amount of egg shell to sawdust,the activation temperature is 800 ℃,and the activation time is 2 h,the specific surface area of AC-1 is 2 009 m2/g,and the mesoporous rate is 70.5%.The optimal adsorption capacity of AC-1 for CR is as high as 862.1 mg/g.The adsorption process is a single-layer composite adsorption process dominated by chemical adsorption.It conforms to the quasi-second-order kinetic model and Langmuir isotherm model.

K2C2O4egg shellmesoporous activated carbonadsorptionCongo red

张诗苑、闫宇星、齐有、曹青

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太原理工大学化学学院,山西太原 030024

太原理工大学化学工程与技术学院,山西太原 030024

K2C2O4 鸡蛋壳 介孔活性炭 吸附 刚果红

山西省重点研发计划高新技术领域项目

201703D121037-1

2024

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
年,卷(期):2024.53(5)