首页|AMPS单体和缔合单体的引入对聚合物流变性及驱油性能影响研究

AMPS单体和缔合单体的引入对聚合物流变性及驱油性能影响研究

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研究了引入AMPS单体形成的超高分多元共聚物(HMWP)和引入缔合单体形成的超高分缔合聚合物(AP-P5)的流变性能与驱油性能。室内实验表明,引入AMPS单体和缔合单体均可以显著提高聚合物的增黏性能与黏弹性能。浓度为2 000 mg/L时,相对于常规聚合物,AP-P5 与HMWP黏度分别提高250。0%和85。1%,黏弹复合模量分别提高36。7%和34。3%,60 d 黏度保留率分别为 60。9%和 82。6%;静态吸附实验发现,HMWP 浓度超过200 mg/L,吸附量趋于平衡,而AP-P5 随着浓度的增加吸附量逐渐增加;驱油实验结果表明,AP-P5 与HMWP的提高采收率幅度分别为11。0%和15。7%,因此,引入AMPS单体更有利于高温高盐油藏聚合物驱油效果提升。现场实验表明,HMWP降水增油效果显著,可以为胜利油田高温高盐油藏大幅度提高采收率提供技术支持。
Effects of introducing AMPS monomer and conjugate monomer on rheological property and oil displacement efficiency of polymers
The hydraulic properties and oil displacement properties of ultra-high molecular weight copoly-mer(HMWP)formed by the AMPS monomer and ultra-high molecular weight conjugated polymer(AP-P5)formed by the conjugate monomer were studied.Laboratory experiments showed that the introduction of AMPS monomer and conjugate monomer could significantly improve the viscosity and viscoelastic prop-erties of polymer.At a concentration of 2 000 mg/L,the viscosity of AP-P5 and HMWP increased by 250.0%and 85.1%,the viscoelastic composite modulus increased by 36.7%and 34.3%,respectively,and the 60 d viscosity retention rate were 60.9%and 82.6%,respectively,relative to the conventional polymer.Static adsorption experiments showed that when the concentration of HMWP exceeded 200 mg/L,the adsorption capacity reached balance,while that of AP-P5 increased with the increase of the concentra-tion.The results of oil displacement experiments showed that the recovery improvement of AP-P5 and HM-WP was 11.0%and 15.7%,respectively.Therefore,the introduction of AMPS monomer is more condu-cive to the improvement of polymer flooding effect in the high-temperature and high-salt reservoirs.Field tests showed that the effect of decreasing produced water and increasing oil was remarkable for HMWP,which can provide a technical support for greatly improving oil recovery in the high temperature and high salt reservoirs in Shengli oilfield.

temperature and salt resistanceultra-high molecular weight copolymerrheologyoil dis-placement efficiency

李海涛、崔传智、徐辉、季岩峰

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胜利油田分公司勘探开发研究院,山东 东营 257015

中国石油大学(华东),山东 青岛 266580

耐温抗盐 超高分多元共聚物 流变性 驱油效果

国家自然科学基金项目

U21B2070

2024

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
年,卷(期):2024.53(6)
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