摘要
综述了萘系双环芳烃的结构特性、应用领域及其对环境和健康的潜在影响.对非催化热缩聚、压力诱导缩聚以及多种催化缩聚方法进行了详细分析,特别是对AlCl3、HF/BF3、过渡金属和固体超强酸SO2-4/Mx Oy等催化机制进行了深入探讨,揭示其缩聚反应的机理、优势与局限性.最后提出了在萘系双环芳烃缩聚领域尚未解决的问题和挑战,为推动相关领域的科学研究和技术发展提供了深入的参考.
Abstract
This paper reviews the structural characteristics,application fields,and potential impacts on the environment and health of naphthalene-based PAHs.It provides a detailed analysis of non-catalytic ther-mal condensation,pressure-induced condensation,and various catalytic condensation methods,especially the catalytic mechanisms of AlCl3,HF/BF3,transition metals,and solid superacids SO2-4/MxOy,revealing their condensation reaction mechanisms,advantages,and limitations.Finally,the unresolved issues and challenges in the field of naphthalene-based PAH condensation are proposed,providing an in-depth refer-ence for promoting scientific research and technological development in related fields.
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