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垃圾焚烧飞灰特性及其重金属固化/稳定化研究进展

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通过对比分析飞灰重金属固化/稳定化技术发现,化学药剂稳定法在处理飞灰方面操作简单、能耗低,容易实现飞灰规模化处置,但也存在化学药剂价格昂贵的问题。若利用化学添加药剂协同机械化学法固化稳定飞灰重金属,在机械力作用下能与重金属化合物发生反应,可生成难溶性重金属化合物以达到稳定重金属的效果,处置过程能耗低、添加剂量少并且能同时稳定多种重金属,有望规模化实现飞灰的无害化及后续的资源化利用。处置后飞灰重金属的浸出风险易受环境因素影响,不同浸出阶段控制机制也不同,常用的环境风险指数法(RAC)在计算处置后飞灰环境风险时只考虑弱酸提取态占比情况可能会导致评估结果的差异,为准确预测处置后飞灰环境风险,多种评价方法结合评估处置后飞灰环境风险或许更能体现评估结果的准确性。研发高效经济的化学添加剂协同机械化学法固化稳定飞灰重金属,是实现飞灰无害化的重中之重,并且飞灰环境风险评估体系也有待进一步修缮。
Research progress on the characteristics of waste incineration fly ash and its heavy metal solidification/stabilization
By comparing and analyzing the solidification/stabilization technology of heavy metals in fly ash,it is found that the chemical stabilization method is simple in operation,low in energy consumption,and easy to realize the large-scale disposal of fly ash,but there is also a problem of expensive chemicals.If the chemical additive agent is combined with the mechanochemical method to dispose the heavy metals in fly ash,it can react with heavy metal compounds under the action of mechanical force,and generate in-soluble heavy metal compounds to achieve the effect of stabilizing heavy metals.The disposal process has low energy consumption,less additive amount and can stabilize multiple heavy metals at the same time,which is expected to realize the harmless and resource utilization of fly ash on a large scale.In addition,the leaching risk of heavy metals in fly ash after disposal is easily affected by environmental factors,and the control mechanism of different leaching stages is also different.The commonly used environmental Risk assessment code(RAC)only considers the proportion of mild acido-soluble fraction state when cal-culating the environmental risk of fly ash after disposal,which may lead to differences in the evaluation re-sults.In order to accurately predict the environmental risk of fly ash after disposal,a combination of multi-ple evaluation methods to evaluate the environmental risk of fly ash after disposal may better reflect the accuracy of the evaluation results.The development of new effective and low-cost chemical stabilizers combined with mechanochemical methods to treat heavy metals in fly ash is an important means to control heavy metals in waste incineration fly ash,and it is necessary to further improve the environmental risk as-sessment system of fly ash after disposal.

fly ashphysical and chemical propertieshevy metal formsleaching propertiesenviron-mental risks

周海、陈敏、彭亚旗、周育智、丁佳敏、孙远、陈孝杨

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安徽理工大学 地球与环境学院,安徽 淮南 232001

浙江大学 台州研究院,浙江 台州 318000

安徽理工大学 安徽省院士工作站,安徽 淮南 232001

浙江大学 能源工程学院,浙江 杭州 310027

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飞灰 理化特性 重金属形态 浸出特性 环境风险

浙江省科技计划领雁计划国家自然科学基金资助项目

2022C0305641572333

2024

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
年,卷(期):2024.53(6)
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