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耐高温深穿透有机延迟交联酸复合体系的制备及性能评价

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为实现碳酸盐岩储层高温井及深井中的延长反应和深穿透作用,创新使用钛离子缓释原理,自制了可在高温、高浓度盐酸条件下交联有机酸的交联剂OAC-1,形成了耐高温深穿透有机延迟交联酸复合体系,并对其耐温耐剪切性、破胶性、降滤失性及携砂能力进行了评价。结果表明,该体系可延迟198 s后进行交联,在温度150 ℃,剪切速率170 s-1条件下,连续剪切100 min后,黏度仍然保持在55 mPa·s以上,具有良好的延迟交联性和耐温耐剪切性。
Preparation and performance evaluation of high-temperature deep-penetrating organic delayed crosslinked acid composite system
To achieve prolonged reaction and deep penetration in high-temperature and deep wells in car-bonate reservoirs,this study innovatively applies the titanium ion slow-release principle.A crosslinking agent,OAC-1,which can crosslink organic acids under high-temperature and high-concentration hydro-chloric acid conditions.This has resulted in a high-temperature,deep-penetrating organic delayed crosslinking acid composite system,and evaluated its temperature resistance,shear resistance,gel break-ing,filter loss reduction,and sand-carrying capacity.The results showed that the crosslinking could be delayed for 198 s,and the viscosity remained above 55 mPa·s for 100 min at 150 ℃ and 170 s-1 shear rate,it has good delayed crosslinking and heat resistance and shear resistance.

organic acid crosslinkerhigh temperature resistancedeep penetrationdelayed crosslink-ingcrosslinked acidfracturing acidification

鄢宇杰、王彦玲、侯帆、罗攀登、史文静

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中国石油大学(华东)石油工程学院,山东青岛 266580

中石化西北油田分公司石油工程技术研究院,新疆乌鲁木齐 830011

有机酸交联剂 耐高温 深穿透 延迟交联 交联酸 压裂酸化

国家自然科学基金企业创新发展联合基金集成项目

U22B6005

2024

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
年,卷(期):2024.53(7)