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改性牡蛎壳对磷吸附性能的研究

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研究了不同牡蛎壳改性方式对磷吸附性能的影响。比较了不同AlCl3改性浓度对牡蛎壳除磷效果,结果表明,0。5 mol/L AlCl3改性牡蛎壳除磷率高达90%,处理后剩余污水磷浓度为0。05 mg/L。研究对比了天然牡蛎壳、热改性牡蛎壳、AlCl3改性牡蛎壳对低浓度含磷污水的处理效果,其TP去除率分别为:63%~68%,61%~72%,83%~90%,AlCl3改性牡蛎壳的TP去除率最高。天然牡蛎壳、热改性牡蛎壳、AlCl3改性牡蛎壳的吸附均符合准二级动力学模型和Freundlich等温吸附模型,吸附过程既有物理吸附也有化学吸附。天然牡蛎壳、热改性牡蛎壳、AlCl3改性牡蛎壳在Freundlich等温吸附模型中参数n值分别为:1。205,1。168,2。611,表明AlCl3改性牡蛎壳对磷的吸附反应比天然牡蛎壳、热改性牡蛎壳对磷的吸附反应更容易进行。
Study on phosphorus adsorption properties of modified oyster shell
The influence of different modification methods of oyster shells on phosphorus adsorption prop-erties were studied.The effect of different modified concentrations of AlCl3 on phosphorus removal in oys-ter shells was compared.The results showed that the phosphorus removal rate of 0.5 mol/L AlCl3 modified oyster shells was as high as 90%,and the phosphorus concentration of residual sewage after treatment was 0.05 mg/L.The study compared the treatment effects of natural oyster shells,hot-modified oyster shells and AlCl3 modified oyster shells on low-concentration phosphorus containing wastewater.The TP removal rate were 63%~68%,61%~72%and 83%~90%,respectively,and the TP removal rate of AlCl3 modified oyster shells were the highest.The adsorption of natural oyster shells,thermal modified oyster shells and AlCl3 modified oyster shells conforms to the quasi-second-order kinetic model and Freundlich isothermal adsorption model,and the adsorption process includes both physical adsorption and chemical adsorption.In the Freundlich isothermal adsorption model,parameter n values of natural oyster shell,hot-modified oyster shell and AlCl3 modified oyster shell were 1.205,1.168 and 2.611,respectively,indica-ting that the adsorption reaction of phosphorus on AlCl3 modified oyster shell was easier than that on natu-ral oyster shell and hot-modified oyster shell.

oyster shellmodificationphosphorus removaladsorption

马雨婷、孔宇、管凛、荆肇乾

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南京林业大学土木工程学院,江苏南京 210037

南京市市政设计研究院有限责任公司,江苏南京 210008

牡蛎壳 改性 除磷 吸附

国家科技支撑计划江苏省产学研合作项目南京市建设行业科技计划项目

2015BAL02B04FZ20220028KS22420

2024

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
年,卷(期):2024.53(7)