首页|含酰胺基团的新型糖基表面活性剂的合成及乳化性能

含酰胺基团的新型糖基表面活性剂的合成及乳化性能

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采用月桂酸、1,3-丙二胺、葡萄糖等化合物为原料,经过酯化反应、胺酯交换反应和还原胺化反应,合成了一种含酰胺和仲胺基团的新型葡萄糖基表面活性剂N'-Glu-N-(3-氨基丙基)月桂酸酰胺(C12-2N-Glu),通过核磁氢谱(1HNMR)、红外光谱(FTIR)、质谱对其结构进行表征。通过表面张力仪测试了表面活性,结果表明,该表面活性剂的临界胶束浓度(cmc)和γcmc分别为0。26 mmol/L和30。86 mN/m,具有非常好的胶束聚集能力和降低水表面张力的能力。且具有较好的乳化性能,乳状液可以在室温下稳定1个月以上,且该乳状液具有良好的pH响应性,有望在智能材料领域有潜在的应用。
Novel emulsions formed by a new glycosyl surfactants containing an amide group
Taking the lauric acid,1,3-propanediamine,and glucose as the raw materials,a novel glycosyl surfactants(C12-2N-Glu)containing amide group and secondary amine groups was successfully synthe-sized through esterification,amine ester exchange and reduced amination reactions.Its structure was char-acterized by FTIR,1H NMR and ESI-MS to demonstrate its purity.The surface activity of the surfactant was tested by a surface tension meter.The results showed that the critical micelle concentration and γcmc of the surfactant were 0.26 mmol/L and 30.86 mN/m,respectively,which possessed very good micelle ag-gregation ability and the ability to reduce the surface tension of water.The surfactant has good emulsifica-tion ability.The oil-in-water emulsions stabilized by C12-2N-Glu can be stored at room temperature for at least one month.The emulsions also show sensitive pH responsiveness,indicating their potential applica-tions in smart systems.

novel surfactantsglycosamideemulsification abilitypH responsiveness

潘婷、裴晓梅、崔正刚、宋冰蕾

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江南大学化学与材料工程学院合成与生物胶体教育部重点实验室,江苏无锡 214122

新型表面活性剂 糖基酰胺 乳化性能 pH响应性

国家自然科学基金项目

22272063

2024

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
年,卷(期):2024.53(7)