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低温热解吸和高温热脱附对土壤三氯乙烯修复效果研究

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针对上海某TCE污染场地土壤,采用Box-Behnken模型因子优化,获得热处理技术应用于TCE修复工程的技术参数。结果表明,"低温热解吸+生石灰"工艺适用于低浓度TCE污染土,去除率与生石灰的投加量呈正相关,当温度达到45 ℃时,残留TCE浓度为0。408 mg/kg,达到修复目标;热脱附技术适用于中高浓度TCE污染土,最优拟合模型为二次项模型,R2=0。92;TCE污染浓度对土壤TCE残留浓度呈强正相关,脱附时间呈负相关,含水率呈弱负相关,各因子对热脱附处理后土壤TCE残留浓度的影响顺序为:TCE污染浓度>脱附时间>含水率。
Remediation of TCE contaminated soil by thermal treatment:Low temperature and high temperature
The Box-Behnken model was used to optimize the soil of a TCE contaminated site in Shanghai,and the technical parameters of the heat treatment technology applied to the TCE remediation project were obtained.The results show that the process of"low temperature thermal desorption+quicklime"is suit-able for low concentration TCE contaminated soil,and the removal rate is positively correlated with the amount of quicklime added.When the temperature reaches 45 ℃,the residual TCE concentration is 0.408 mg/kg,reaching the remediation target.Thermal desorption technique is suitable for medium and high concentration TCE contaminated soil.The optimal fitting model is quadratic model with R2=0.92.TCE pollution concentration has a strong positive correlation to soil TCE residue concentration,desorption time has a negative correlation,and water content has a weak negative correlation.The order of influence of each factor on soil TCE residue concentration after thermal desorption treatment is TCE pollution con-centration>desorption time>water content.

TCE contaminated soillow temperature thermal desorptionhigh temperature thermal desorptionBox-Behnken modelprocess combination optimization

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上海勘察设计研究院(集团)股份有限公司,上海 200093

上海环境岩土工程技术研究中心,上海 200093

三氯乙烯污染土壤 低温热解吸 高温热脱附 Box-Behnken模型 工艺组合优化

国家重点研发计划

2019YFC1805802

2024

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
年,卷(期):2024.53(7)