应用化工2024,Vol.53Issue(7) :1620-1623,1629.

耐盐两性聚丙烯酰胺的合成及其性能评价

Synthesis and performance evaluation of salt-tolerant amphoteric polyacrylamide

许士杰 杨旭 朱丽莲 李昭滢 冯明月 冯志刚 王嘉兴
应用化工2024,Vol.53Issue(7) :1620-1623,1629.

耐盐两性聚丙烯酰胺的合成及其性能评价

Synthesis and performance evaluation of salt-tolerant amphoteric polyacrylamide

许士杰 1杨旭 1朱丽莲 1李昭滢 1冯明月 1冯志刚 1王嘉兴2
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作者信息

  • 1. 西南石油大学化学化工学院,四川成都 610500
  • 2. 宁夏水投盐池水务有限公司,宁夏吴忠 751500
  • 折叠

摘要

以丙烯酰胺(AM)、2-丙烯酰胺基-2-甲基丙磺酸(AMPS)、二甲基二烯丙基氯化铵(DMDAAC)为单体制备两性聚丙烯酰胺AMPAM,测试耐盐性能.结果表明,AMPAM在20 000 mg/L的NaCl溶液、10 000 mg/L的CaCl2溶液中,仍能保持10 mPa·s以上的黏度.对不同矿化度下0.5%浓度AMPAM溶液,使用SEM扫描电镜对其微观形貌的变化进行了观察,由于分子间引力和斥力的严重削弱,分子链开始靠拢、卷曲,形成大量的分子簇,最终形成完整的块状结构,此时溶液黏度变化很小,并逐渐趋于稳定.

Abstract

Acrylamide(AM),2-acrylamido-2-methylpropanesulfonic acid(AMPS)and dimethyl-diallyl ammonium chloride(DMDAAC)as monomers to prepare amphoteric polyacrylamide,the salt resistance was tested.The result showed that qualitative analysis by infrared spectroscopy and nuclear magnetic reso-nance confirmed that the synthesized product was the target product,and AMPAM can maintain a viscosity of more than 10 mPa·s in 20 000 mg/L NaCl solution and 10 000 mg/L CaCl2 solution.Scanning elec-tron microscopy was used to observe the changes in the microscopic morphology of AMPAM solution with 0.5%concentration at different salinity.Due to the serious weakening of intermolecular attraction and repulsion,the molecular chains began to converge and curl,forming a large number of molecular clusters and eventually forming a complete block structure.At this time,the viscosity of the solution changed little and gradually became stable.

关键词

两性聚丙烯酰胺/合成/耐盐性能/聚合物

Key words

amphoteric polyacrylamide/synthetic/salt resistance/polymer

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基金项目

四川省自然科学基金项目(2022NSFSC1002)

出版年

2024
应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
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