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耐盐两性聚丙烯酰胺的合成及其性能评价

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以丙烯酰胺(AM)、2-丙烯酰胺基-2-甲基丙磺酸(AMPS)、二甲基二烯丙基氯化铵(DMDAAC)为单体制备两性聚丙烯酰胺AMPAM,测试耐盐性能。结果表明,AMPAM在20 000 mg/L的NaCl溶液、10 000 mg/L的CaCl2溶液中,仍能保持10 mPa·s以上的黏度。对不同矿化度下0。5%浓度AMPAM溶液,使用SEM扫描电镜对其微观形貌的变化进行了观察,由于分子间引力和斥力的严重削弱,分子链开始靠拢、卷曲,形成大量的分子簇,最终形成完整的块状结构,此时溶液黏度变化很小,并逐渐趋于稳定。
Synthesis and performance evaluation of salt-tolerant amphoteric polyacrylamide
Acrylamide(AM),2-acrylamido-2-methylpropanesulfonic acid(AMPS)and dimethyl-diallyl ammonium chloride(DMDAAC)as monomers to prepare amphoteric polyacrylamide,the salt resistance was tested.The result showed that qualitative analysis by infrared spectroscopy and nuclear magnetic reso-nance confirmed that the synthesized product was the target product,and AMPAM can maintain a viscosity of more than 10 mPa·s in 20 000 mg/L NaCl solution and 10 000 mg/L CaCl2 solution.Scanning elec-tron microscopy was used to observe the changes in the microscopic morphology of AMPAM solution with 0.5%concentration at different salinity.Due to the serious weakening of intermolecular attraction and repulsion,the molecular chains began to converge and curl,forming a large number of molecular clusters and eventually forming a complete block structure.At this time,the viscosity of the solution changed little and gradually became stable.

amphoteric polyacrylamidesyntheticsalt resistancepolymer

许士杰、杨旭、朱丽莲、李昭滢、冯明月、冯志刚、王嘉兴

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西南石油大学化学化工学院,四川成都 610500

宁夏水投盐池水务有限公司,宁夏吴忠 751500

两性聚丙烯酰胺 合成 耐盐性能 聚合物

四川省自然科学基金项目

2022NSFSC1002

2024

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
年,卷(期):2024.53(7)