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有机改性膨润土对废水中四环素的吸附研究

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针对天然膨润土(Bt)对废水中的四环素去除效果不佳问题,采用十二烷基二甲基甜菜碱(BS-12)对Bt进行改性,制备出BS-12改性膨润土(BS-Bt)吸附材料,研究了 BS-Bt和Bt对废水中四环素的吸附性能,并考察吸附剂的投加量、溶液pH、离子强度对吸附过程的影响。结果表明,Bt和BS-Bt吸附四环素的能力随吸附剂加入量的减小而增大;随着四环素废水溶液pH的增大而减小;随着离子强度的增强表现出缓慢减小的趋势。Bt和BS-Bt在1 h内快速完成对四环素的吸附,4 h达到吸附平衡,符合准二级动力学方程(R2>0。996),Freundlich模型对吸附数据具有良好的非线性拟合性,吸附等温线均呈"L型"。经两性表面活性剂改性的膨润土对四环素的吸附性能明显高于原土,这使其成为四环素废水处理的潜在吸附剂。
Adsorption of tetracycline in wastewater by organic modified bentonite
In response to the poor removal effect of tetracycline from wastewater by natural bentonite(Bt),BS-12 was used to modify Bt and prepare BS-12 modified bentonite(BS-Bt)adsorption material,studied the adsorption performance of BS-Bt and Bt on tetracycline in wastewater,and the dosage of adsorbent pH and ionic concentrations were discussed.The results show that the adsorption capacity of Bt and BS-Bt for tetracycline increases with the decrease of adsorbent addition amount;with the increase of pH;with the Ca2+concentrations increasing,the adsorption capacity present slowly decreasing trend.The adsorption process of tetracycline by Bt and BS-Bt could be completed rapid adsorption within 1 h,and reached adsorption equilibrium within 4 h,it conforms to the quasi-second order dynamic equation(R2>0.996).The Freundlich model has good nonlinear fitting ability for adsorption data,and adsorption isotherms are"L-type".The adsorption capacity of organically-modified bentonite to tetracycline was significantly higher than that of bentonite,which made it a potential adsorbent for tetracycline wastewater treatment.

organic modificationbentoniteadsorptiontetracycline

柴琴琴、杨平平、周恺、张小燕、刘建伟

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西安汉唐分析检测有限公司,陕西西安 710016

西安科技大学化学与化工学院,陕西西安 710054

有机改性 膨润土 吸附 四环素

陕西省青年科技新星人才项目

2023KJXX-125

2024

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
年,卷(期):2024.53(7)