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粉煤灰制备高分子絮凝剂研究进展

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总结了粉煤灰在酸碱体系中主要元素溶出行为。粉煤灰在酸性体系中主要浸出铝铁元素且铁元素浸出率远高于铝元素;在碱性体系中主要溶出硅铝元素且硅元素溶出率远高于铝元素。硅铝以非晶相状态存在,单独酸浸、碱溶对硅铝提取率较低,采用高温助熔结合酸浸、碱溶工艺可使硅铝断键提高元素提取率。对粉煤灰合成絮凝剂的种类进行归纳,根据粉煤灰制备絮凝剂的化学组分将其分为无机高分子絮凝剂和无机-有机杂化高分子絮凝剂,其中无机高分子絮凝剂按其阴离子系列所含酸根的数量和种类,分为一元酸、二元酸及多元酸系列,阴离子酸根以硅酸根、硫酸根、氯离子及磷酸根为主。对粉煤灰合成絮凝剂的发展及亟待解决的问题进行展望。
Research progress in the preparation of polymer flocculants from fly ash
The dissolution behavior of the main elements of fly ash in acid-base systems.Fly ash mainly leaches aluminum-iron elements in the acid system,and the leaching rate of iron is much higher than that of aluminum.Under alkaline conditions,silicon-aluminum elements are mainly dissolved,and the leaching rate of silicon elements is much higher than that of aluminum elements.Silicon aluminum exists in the amorphous phase state,and the extraction rate of silicon aluminum is low by acid leaching and alkali solu-tion alone,and the use of high temperature melting combined with acid leaching and alkaline solution process can make silicon aluminum bond break and improve the element extraction rate.The types of fly ash synthetic flocculants are summarized,and they are divided into inorganic polymer flocculants and inor-ganic-organic hybrid polymer flocculants according to the chemical components of fly ash to prepare floc-culants,among which inorganic polymer flocculants are divided into monoacids,diacids and polyacids ac-cording to the number and types of acids contained in their anion series,and anionic acids are mainly sili-cate,sulfate,chloride ion and phosphate.The development of fly ash synthetic flocculants and the prob-lems to be solved urgently are prospected.

fly ashpolymer flocculantflocculant preparationwater treatment

崔红梅、李凯欣、孙林阳、祝凤蕊、张颖、齐晗兵

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东北石油大学土木建筑工程学院,黑龙江大庆 163318

黑龙江省寒区新能源热利用及防灾减灾重点实验室,黑龙江大庆 163318

天津渤化工程有限公司,天津 300193

辽宁省城乡建设规划设计院有限责任公司,辽宁沈阳 110000

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粉煤灰 高分子絮凝剂 絮凝剂制备 水处理

黑龙江省自然科学基金项目东北石油大学青年科学基金项目

LH2019E0152019QNL-30

2024

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
年,卷(期):2024.53(7)