应用化工2024,Vol.53Issue(8) :1761-1764.

改性玉米芯生物炭与钢渣微粉组合吸附磷的研究

Study on adsorption of phosphorus and hydrochloricacid by the combination of modified corncob biochar and steel slag micropowder

李雨桐 孔宇 管凛 荆肇乾
应用化工2024,Vol.53Issue(8) :1761-1764.

改性玉米芯生物炭与钢渣微粉组合吸附磷的研究

Study on adsorption of phosphorus and hydrochloricacid by the combination of modified corncob biochar and steel slag micropowder

李雨桐 1孔宇 2管凛 2荆肇乾1
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作者信息

  • 1. 南京林业大学 土木工程学院,江苏 南京 210037
  • 2. 南京市市政设计研究院有限责任公司,江苏 南京 210008
  • 折叠

摘要

探究镁改性玉米芯生物炭和钢渣微粉以及两者组合对含磷模拟废水的吸附效果.结果表明,5 g玉米芯粉末在10 mL的1.5 mol/L浓度MgCl2 改性条件下,在热解温度为450℃的马弗炉中烧制的生物炭对磷吸附效果最佳.钢渣微粉与镁改性玉米芯生物炭组合的添加量由 14g/L钢渣微粉和 4g/L镁改性玉米芯生物炭混合组成.钢渣微粉与镁改性玉米芯生物炭组合对磷的吸附效果均好于两者单独存在时,去除率高达98%,并在60 min时吸附达到平衡,组合投加吸附平衡时间均短于两种材料分别单独存在时.组合投加吸附过程满足准二级吸附动力学模型,且符合Langmuir等温吸附方程,最大理论吸附量为0.12 mg/g.

Abstract

The adsorption effect of magnesium modified corncob biochar,steel slag powder and their com-bination on phosphorus-containing simulated wastewater was investigated.The results showed that the bio-char produced by 5 g corncob powder modified by 10 mL of 1.5 mol/L MgCl2 in muffle furnace with py-rolysis temperature of 450℃could adsorb phosphorus.The addition of steel slag powder and magnesium modified corncob biochar is composed of 14 g/L steel slag powder and 4 g/L magnesium modified corncob biochar.The adsorption effect of the combination of steel slag powder and magnesium modified corncob biochar on phosphorus was better than that of the combination of steel slag powder and magnesium modi-fied corncob biochar,the removal rate was up to 98%and the adsorption reached equilibrium in 60 min,and the adsorption equilibrium time was shorter than that of the combination of the two materials.Com-bined dosage adsorption quasi-second-order adsorption kinetics model and Langmuir isothermal adsorption equation,the maximum theoretical adsorption capacity is 0.12 mg/g.

关键词

改性生物炭/磷酸盐/玉米芯/钢渣/吸附

Key words

modified biochar/phosphate/corn cob/steel slag/adsorb

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基金项目

国家科技支撑计划(2015BAL02B04)

江苏省产学研合作项目(FZ20220028)

南京市建设行业科技计划项目(KS22420)

出版年

2024
应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
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