首页|轻质重质原油掺配比例对石油沥青路用性能和结构的影响

轻质重质原油掺配比例对石油沥青路用性能和结构的影响

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分别选取一种轻质原油和一种重质原油,按照不同比例进行复配,采用常减压蒸馏工艺制备沥青。研究原油掺配比例对沥青物理性能和流变性能的影响,通过傅里叶红外光谱仪测试并计算原油和沥青中各官能团指数,研究了原油炼制沥青过程中官能团指数的变化,基于灰色关联分析方法建立沥青官能团指数与其路用性能间的关联。结果表明,随着轻质原油的掺入,沥青的针入度和延度呈增大趋势,软化点、旋转黏度、复数模量和车辙因子呈减小趋势;炼制过程中脂肪族相对含量减小,苯环上的=C—H和亚砜基相对含量增加;芳香族含量主要决定针入度和软化点,脂肪族对延度影响较大,苯环上的=C—H与旋转黏度、复数模量和车辙因子关联性较大。
Effect of mixing ratio of light and heavy cude oils on road properties and structure of petroleum aphalt
One kind of light crude oil and one kind of heavy crude oil were selected respectively,blended in different ratios,and asphalt was prepared by atmospheric and vacuum distillation process.Research on the impact of crude oil blending ratio on the physical properties and rheological properties of asphalt,Fou-rier spectroscopic tests were performed and functional group indices of crude oil and asphalt were calculat-ed,the study of crude oil refining asphalt in the process of the change of the functional group index,based on the gray relational analysis method to establish the correlation between the functional group index of as-phalt and its road performance.The results show that,with the incorporation of light crude oil,the penetra-tion and ductility of asphalt tend to increase,and the softening point,rotational viscosity,complex modulus and rutting factor tend to decrease;the relative content of aliphatic groups during the refining process de-creases,and the relative content of=C—H on the benzene ring and sulfoxide group increases;the con-tent of aromatic groups mainly determines the penetration and softening point,and aliphatic groups have a greater impact on the ductility,and=C—H on the benzene ring is related to the rotational viscosity,com-plex modulus and rutting factor.

crude oilasphalt propertiesFTIRgrey relational analysis

臧广远、祁聪、李冠玉、李启仲、况栋梁、韩善剑、陈华鑫

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长安大学 材料科学与工程学院,陕西 西安 710064

京博(海南)新材料有限公司,海南 儋州 571700

山东海韵沥青有限公司,山东 滨州 256600

海南省交通投资控股有限公司,海南 海口 570203

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原油 沥青性能 傅里叶变换红外光谱 灰关联分析

国家自然科学基金面上项目海南省重点研发专项"揭榜挂帅"项目陕西省秦创原"科学家+工程师"队伍建设项目

52178410ZDYF2023GXJS1472022KXJ-004

2024

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
年,卷(期):2024.53(8)