首页|玉米芯纤维素基保水保肥材料的制备及性能研究

玉米芯纤维素基保水保肥材料的制备及性能研究

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使用玉米芯纤维素结合羧甲基化修饰制备高吸水性水凝胶,引入氨氮吸附功能,制备出一种高效保水保肥材料CCH/Z,通过SEM、FTIR、接触角等测试对其微观结构、官能团组成、亲水性进行了分析,并通过吸水溶胀实验和氨氮吸附实验,测试了合成材料的保水保肥性能。结果表明,CCH/Z保水率可达到452。49%,在保肥方面,当CCH/Z用量为0。15 g时,在100 mg/L氨氮溶液中,吸附率可达41。4%,准一级动力学模型、准二级动力学模型均可以描述吸附氨氮行为,热力学分析表明,CCH/Z的吸附行为符合Freundlich模型。
Preparation and properties of corn cob cellulose-based water and fertilizer retention materials
Corncob cellulose combined with carboxymethylation was used to prepare a superabsorbent hydrogel,ammonia nitrogen adsorption was introduced to prepare a highly efficient water and fertilizer retention material(CCH/Z).The microstructure,functional group composition and hydrophilicity of the syn-thetic material were analyzed by SEM,FTIR and contact Angle tests.The water and fertilizer retention per-formance of the synthetic material was tested by water swelling experiment and ammonia nitrogen adsorption experiment.The results showed that the water retention rate of CCH/Z could reach 452.49%.In terms of fertilizer retention,the adsorption rate in 100 mg/L ammonia nitrogen solution could reach 41.4%when the amount of CCH/Z was 0.15 g.Both the pseudo-first-order kinetic model and the pseudo-second-order model kinetic model can describe the ammonia nitrogen adsorption behavior of CCH/Z.Thermodynamic analysis showed that the adsorption behavior of CCH/Z was in accordance with the Freundlich model.

corn cob cellulosewater-retaining materialsfertilizer preservation materialshydrogel

张新浩、李莎、贾睿、YASSINE Mouham、罗钰、邢建宇

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长安大学水利与环境学院,陕西西安 710054

长安大学旱区地下水文与生态效应教育部重点实验室,陕西西安 710054

长安大学水利部旱区生态水文与水安全重点实验室,陕西西安 710054

玉米芯纤维素 保水材料 保肥材料 水凝胶

陕西省自然科学基础研究计划资助项目陕西省教育厅科学研究计划项目资助

2020JM-22622JE003

2024

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
年,卷(期):2024.53(9)