首页|掺杂ZIF-8改性全水发泡聚氨酯泡沫

掺杂ZIF-8改性全水发泡聚氨酯泡沫

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在常温的水中利用2-甲基咪唑和六水合硝酸锌制备了多孔低密度材料沸石咪唑框架-8(ZIF-8),用环保溶剂水为发泡剂,采用一步法制备出具有保温隔热能力的聚氨酯泡沫(PUF),探讨ZIF-8用量对聚氨酯泡沫性能的影响。结果表明,添加少量的ZIF-8可明显改善聚氨酯泡沫的各项性能;当ZIF-8掺杂量(质量分数)为1%时,聚氨酯泡沫的导热系数降低了 18%,压缩强度提高了 14。5%。促进全水发泡的聚氨酯泡沫在隔热方面工业化发展。
Modification of all-water foamed polyurethane foam by doping ZIF-8
Porous low-density zeolite imidazole framework-8(ZIF-8)was prepared by using 2-methylimid-azole and zinc nitrate hexahydrate in water at room temperature polyurethane foam(PUF)with thermal in-sulation ability was prepared by one-step method with water as foaming agent.The influence of ZIF-8 on the polyurethane foams performace.The results show that adding a small amount of ZIF-8 can obviously improve the properties of polyurethane foam.When the doping amount of ZIF-8 is 1%,the thermal con-ductivity of polyurethane foam decreases by 18%,the compressive strength increases by 14.5%,and the hardness also increases obviously.It paves the way for the industrialization of all-water foamed polyure-thane foam in heat insulation.

polyurethanefoamszeolite imidazole framework-8thermal conductivitymechanical properties

廉兆龙、王彩凤、王帅、孙彬、李晓屿

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辽宁石油化工大学石油化工学院,辽宁抚顺 113001

聚氨酯材料 泡沫 沸石咪唑框架-8 导热系数 力学性能

辽宁省教育厅自然科学基金项目辽宁省教育厅自然科学基金项目

L2019031L2019041

2024

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
年,卷(期):2024.53(9)