应用化工2024,Vol.53Issue(10) :2257-2262.

水热法活化钾长石工艺过程优化

Optimization of hydrothermal activation process of potassium feldspar

杨会国 杜赛权 马丽萍 赵尚伟 边腾 冯宽 化全县
应用化工2024,Vol.53Issue(10) :2257-2262.

水热法活化钾长石工艺过程优化

Optimization of hydrothermal activation process of potassium feldspar

杨会国 1杜赛权 1马丽萍 1赵尚伟 1边腾 1冯宽 1化全县1
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作者信息

  • 1. 郑州大学 化工学院 国家钙镁磷复合肥技术研究推广中心,河南 郑州 450000
  • 折叠

摘要

对氧化钙和钾长石水热化学法提钾的工艺过程进行了研究和条件优化.在对反应助剂进行筛选的基础上,探讨了反应时间、反应温度、液固比和nCa/n(Si+Al)对钾长石活化提钾的影响.通过正交实验,确定了钾长石活化提钾的最优工艺.并利用X射线衍射和傅里叶红外研究了处理后的滤渣的晶型情况.结果表明,优选的碱基反应助剂CaO,在最佳的反应条件下,钾的浸取率最高为89.24%.处理后的钾长石滤渣主要由完整度和结晶度较好的钾霞石、水钙铝榴石和葡萄石构成,显示钾长石晶体结构被破坏.

Abstract

The process of extracting potassium from calcium oxide and potassium feldspar by hydrothermal chemical method was studied and the conditions were optimized.The effects of reaction time,reaction tem-perature,liquid-solid ratio and nCa/n(Si+Al)on the activation of potassium feldspar were discussed.Through orthogonal test,the optimum technology of potassium feldspar activation extraction was deter-mined.The crystal shape of the treated filter slag was studied by X-ray diffraction and Fourier infrared.The results showed that the leaching rate of potassium is up to 89.24%under the optimum reaction con-dition of CaO.After treatment,the filter residue is mainly composed of potassium nepheline,hydrocalcium-aluminite and grape stone with good integrity and crystallinity,indicating that the crystal structure of po-tassium feldspar has been destroyed.

关键词

钾长石/水热法/碱基活化/浸取率/

Key words

potash feldspar/hydrothermal process/base activation/dissolution rate/potassium

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基金项目

国家重点研发计划(2018YFD0200606)

河南省大学生创新创业训练计划(202310459120)

出版年

2024
应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
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