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聚乙二醇改性油酸的性能研究

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为提高液压液的稳定性,保障液压支架跟机移架的可靠性,研究了4 个厂家的油酸和其改性后的产物对液压液粒径的影响,通过气质联用分析各油酸的组成,采用醇胺和聚乙二醇分别对油酸进行改性,考察了改性油酸在水溶液中的润滑性、表面张力、pH值、电导率、Zeta电位和粒径,及不同配液浓度下,含改性油酸液压液的粒径。结果表明,在500 mg/L的人工硬水中,醇胺改性油酸产生沉淀,聚乙二醇改性油酸未产生沉淀;杂质含量较少的油酸,经聚乙二醇改性后,表面张力、Zeta电位较高,粒径较小;在不同配液浓度下,采用聚乙二醇改性油酸制备的液压液比采用醇胺改性相同油酸制备的液压液粒径更小,平均粒径小于 100 nm,液压液的可过滤性更强、稳定性更高。
Study on the properties of oleic acids modified by polyethylene gtlycol
In order to improve the stability of hydraulic fluid and ensure the reliability of hydraulic support following the machine,oleic acid from four manufacturers and the influence on the particle size of hydrau-lic fluid containing modified oleic acid were studied.The composition of each oleic acid was analyzed by GC-MS,and oleic acid was modified by alcohol amine and polyethylene glycol respectively.The lubricity,surface tension,pH value,conductivity,Zeta potential and particle size of modified oleic acid in aqueous solution,as well as the particle size of hydraulic fluid containing modified oleic acid in different liquid concentrations were investigated.The results show that oleic acid modified by alcohol amine can precipi-tate in 500 mg/L artificial hard water,but oleic acid modified by polyethylene glycol can not precipitate.Oleic acid modified by PEG with less impurity content had higher surface tension,higher Zeta potential and smaller particle size.The diameter of the hydraulic fluid prepared by using polyethylene glycol modi-fied oleic acid is smaller than that prepared by using alcohol amine modified oleic acid,the average diam-eter is less than 100 nm,and the hydraulic fluid has stronger filter-ability and higher stability.

polyethylene glycolmodifiedoleic acidssurface tensionZeta potentialparticle sizehydraulic fluid

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煤炭科学技术研究院有限公司,北京 100013

煤科(北京)新材料科技有限公司,北京 100013

煤炭资源高效开采与洁净利用国家重点实验室,北京 100013

聚乙二醇 改性 油酸 表面张力 Zeta电位 粒径 液压液

国家重点研发计划中国煤炭科工集团有限公司重点先进技术产品研发任务煤科院科技发展基金项目

2023YFB41030022023-3-232022CX-Ⅱ-09

2024

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
年,卷(期):2024.53(10)