应用化工2024,Vol.53Issue(10) :2320-2324.

丙烯酸酯接枝木质素磺酸钠共聚物乳液土壤固化剂的合成及性能

Synthesis and properties of acrylate grafted sodium lignosulfonate copolymer iotion soil curing agent

陈玮琦 白晓成 张光华 侯飞帆 杜佳妮 刘银萍 刘瑞珺
应用化工2024,Vol.53Issue(10) :2320-2324.

丙烯酸酯接枝木质素磺酸钠共聚物乳液土壤固化剂的合成及性能

Synthesis and properties of acrylate grafted sodium lignosulfonate copolymer iotion soil curing agent

陈玮琦 1白晓成 2张光华 1侯飞帆 1杜佳妮 1刘银萍 1刘瑞珺1
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作者信息

  • 1. 陕西科技大学 陕西省轻化工助剂重点实验室,陕西 西安 710021
  • 2. 中交二公局东萌工程有限公司,陕西 西安 710119
  • 折叠

摘要

为了研究出稳定性强、经济环保、抗水性良好的有机高分子类土壤固化剂,选取丙烯酸(AA)、丙烯酸丁酯(BA)、苯乙烯(St)为功能单体,以木质素磺酸钠(SLS)进行接枝共聚,利用反应型乳化剂ANPEO10 和DNS-86 提升乳化效率及稳定性,采取预乳化半连续加料方式和种子乳液法进行接枝反应,制得一种新型高分子乳液土壤固化剂PAAB与PAAS,对其进行结构表征和性能测试.结果表明高分子乳液性能稳定,TSI均小于0.2;加入固化土中,其交联网状结构包覆土颗粒,乳液中的功能基团与土壤中阳离子键合,形成凝胶物质,固化土/水表面接触角可达到91.68,99.21,PAAS固化土养护7d后抗压强度可达到368.4 kPa,减小了试样土膨胀率及降低了冻融循环作用对固化土的影响.

Abstract

In order to study the organic polymer soil curing agents with strong stability,economic and envi-ronmental protection,and good water resistance,acrylic acid(AA),butyl acrylate(BA),styrene(St)were selected as the functional monomers,and graft copolymerization was carried out with sodium lignosulpho-nate(SLS),and the reactive emulsifiers ANPEO10 and DNS-86 were used to enhance the emulsification efficiency and stability,and the pre-emulsification semi-continuous dosing and seed emulsion methods were adopted for the grafting reaction.A new type of polymer emulsion soil curing agent PAAB and PAAS was produced by grafting reaction using pre-emulsification semi-continuous charging method and seed e-mulsion method,and its structure was characterized and performance tested.The results show that the pol-ymer emulsion performance is stable TSI are less than 0.2;added to the cured soil,its crosslinked mesh structure encapsulates the soil particles,the functional groups in the emulsion and the soil cation bonding,the formation of gel substances,cured soil/water surface contact angle can reach 91.68,99.21,PAAS cured soil after seven days of maintenance compressive strength of 368.4 kPa,reducing the sample soil expansion and the effect of freeze-thaw cycle on cured soil was reduced.

关键词

土壤固化剂/木质素磺酸钠/无侧限抗压强度/冻融循环/团聚稳定性

Key words

soil stabilizer/sodium lignosulfonate/unconfined compressive strength/freeze-thaw cycle/agglomeration stability

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基金项目

陕西省重点研发计划项目(2023-YBGY-324)

陕西省重点研发计划项目(2021CGBX-22)

出版年

2024
应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
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