首页|碳钢在CO2/H2S共存体系下油田采出水中的腐蚀行为研究

碳钢在CO2/H2S共存体系下油田采出水中的腐蚀行为研究

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CO2、H2S和高矿化度是油田采出水中 3 种常见的腐蚀因素,当 3 种腐蚀因素同时存在时,腐蚀行为远比CO2、H2S和高矿化度单独作用时复杂。利用反应釜模拟高矿化度采出水同时存在CO2 和H2S的实际工况,研究了CO2 分压分别为0。15,0。75,1。5 MPa,H2S分压为0。000 15 MPa,温度为50,60,70℃条件下,20G、L245N 和L360Q三种碳钢的腐蚀行为。结果表明,3 种碳钢在CO2/H2S共存的油田高矿化度采出水体系中均腐蚀严重,在液相中比在气相中腐蚀更为严重,最大腐蚀速率达到 3。4 mm/a,随着腐蚀时间的延长,腐蚀速率整体呈现波动性下降的趋势;随实验温度的提高其腐蚀速率呈总体增大趋势;在 3 种分压条件下,腐蚀速率随CO2 分压增加先增大后减小,在分压0。75 MPa时腐蚀速率最大;3 种材质腐蚀速率大小顺序为L245N>L360Q>20G,则耐蚀顺序为 20G>L360Q>L245N。
Corrosion behavior of carbon steel in oilfield produced water under CO2/H2S coexistent system
CO2,H2S And high salinity are three common corrosion factors in oilfield produced water.When three corrosion factors coexist,the corrosion behavior is much more complex than when CO2,H2S and high salinity act alone.Using the reactor to simulate the actual operating conditions of high salinity produced water with the simultaneous presence of CO2 and H2S,the corrosion behavior of three carbon steels,20G,L245N,and L360Q,was studied under conditions of CO2 partial pressure of 0.15,0.75,1.5 MPa,H2S partial pressure of 0.000 15 MPa,and temperature of 50,60,70℃in the corrosive envi-ronment of high salinity produced water in oil fields.The results indicate that the three types of carbon steel exhibit severe corrosion in high salinity extracted water systems of oil fields where CO2/H2S coex-ists,with a maximum corrosion rate exceeding 3.4 mm/a,and corrosion is more severe in liquid phase than in gas phase.As the corrosion time prolongs,the overall corrosion rate shows a fluctuating downward trend;as the experimental temperature increases,the corrosion rate shows an overall increasing trend;un-der three different partial pressure conditions,the corrosion rate first increases and then decreases with the increase of CO2 partial pressure,and reaches its maximum at a partial pressure of 0.75 MPa;the corrosion rate order of the three materials is L245N>L360Q>20G,and the corrosion resistance order is 20G>L360Q>L245N.

CO2/H2S coexisting systemhigh salinityoilfield produced watercorrosion ratepartial pres-sure

曲虎、陆诗建、林俊岭、马艳辉、刘静

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中国石油工程建设有限公司华北分公司,河北 任丘 062552

中国矿业大学碳中和研究院,江苏 徐州 221116

CO2/H2S共存体系 高矿化度 采出水 腐蚀速率 分压

巴彦"三高"油田高效低碳地面关键技术研究企业自筹科技攻关项目

2022HBKJ01

2024

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
年,卷(期):2024.53(10)