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变压器油色谱分析检测能力评价方法

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采用4 种方法分别对各单位气相色谱仪检测结果进行评价,研究各评价方法在变压器油色谱检测能力评价中的应用效果。结果表明,迭代稳健统计法结合GB/T 17623-2017 中重复性要求的评价结果可信度更高。Z比分数经典统计法严于Z比分数稳健统计法,但二者均存在去真的风险,建议将二者的"不满意"评价标准设定为|Z|≥3 且与GB/T 17623-2017 中重复性要求联用。迭代稳健统计法与Z比分数经典统计法中的箱线图去除异常值结果吻合度较高,只有一台仪器的一个气体检测参量是被箱线图异常值去除而未被迭代稳健统计法去除,其余去除结果均与迭代稳健统计法保持一致,表明迭代稳健统计法在去除异常值方面可信性较高,应用Z比分数经典统计法时,可直接采用箱线图去除异常值进行评价。
Evaluation method for detection capability of dissolved gas analysis in transformer oil
Four kinds of methods were selected to evaluate the chromatography detection results of gas chromatograph from each company,then the application results of each evaluation methods in the evalua-tion of transformer oil chromatographic detection capability were researched.The result showed that the it-erative robust statistical method combined with the repeatability requirements in GB/T 17623-2017 has higher reliability.The Z-score classical statistical method is stricter than the Z-score robust statistical method,but both of them have the risk of over deleted.It is suggested to set the"dissatisfied"evaluation criteria for both of them as|Z|≥3 and apply them in combination with the repeatability requirement in GB/T 17623-2017.The iterative robust statistical method has a high agreement with the boxplot outlier removal results in the Z-score classical statistical method.Besides,only one gas detection parameter of one instrument is removed by the boxplot outlier but not by the iterative robust statistical method,and other re-moval results are all included in the removal results of the iterative robust statistical method.The result showed that the iterative robust statistical method has high credibility in removing outliers,and the boxplot can be used directly to remove outliers for evaluation when the Z-score classical statistical method is ap-plied.

chromatographychemical analysisiterative robust statistical methodrepeatabilityZ-score classical statistical methodbox diagramZ-score robust statistics

石荣雪、刘克成、郁金星、周慧波、韩鹤松、刘思琦

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国网河北省电力有限公司电力科学研究院,河北 石家庄 050021

色谱 化学分析 迭代稳健统计法 重复性 Z比分数经典统计法 箱线图 Z比分数稳健统计法

国网河北能源技术服务有限公司科技项目

TSS2023-12

2024

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
年,卷(期):2024.53(10)