首页|复配淋洗剂对土壤中Cr(Ⅵ)的去除效果研究

复配淋洗剂对土壤中Cr(Ⅵ)的去除效果研究

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选用了7 种表面活性剂两两复配作为淋洗剂,考察其对土壤中Cr(Ⅵ)的洗脱效果及影响因素。结果表明,两性表面活性剂十八烷基二甲基氧化铵(OA-18)相较于其他6 种表面活性剂具有更高的洗脱率,且OA-18 与十二烷基苯磺酸钠(SDBS)混合而成的复配淋洗剂的洗脱效果相较于单一表面活性剂及其他复配淋洗剂的洗脱性能均更好。当OA-18 和SDBS以6∶4的体积比复配,复配淋洗剂浓度为1。2 g/L,溶液pH值为8,振荡淋洗时间为12 h,土水比为1∶15 时洗脱效果最佳,对土壤中Cr(Ⅵ)的去除率为92。3%。
Study on removal effect of compound rinsing agent on Cr(Ⅵ)in soil
This article selected seven surfactants,paired in combinations,as washing agents to investigate their effects on leaching chromium(Ⅵ)from soil and the influencing factors.The results showed that the novel amphoteric surfactant,octadecyl dimethylammonium oxide(OA-18),had a higher leaching rate compared to the other six surfactants.Additionally,the mixed washing agent composed of OA-18 and sodi-um dodecyl benzene sulfonate(SDBS)demonstrated better leaching performance than individual surfac-tants and other tested combination washing agents.The best leaching effect was achieved when OA-18 and SDBS were combined in a volume ratio of 6∶4,with an initial concentration of the mixed washing agent at 1.2 g/L,a solution pH of 8,an oscillating washing time of 12 h,and a soil-to-water ratio of 1∶15.Under these conditions,the removal rate of chromium(Ⅵ)from soil was 92.3%.

surfactantRe-matchhexavalent chromiumsoil washingsoil remediation

甘文涛、王政华、臧翀、牛建敏

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湖南科技大学 土木工程学院,湖南 湘潭 411201

湖南大学 土木工程学院,湖南 长沙 410082

深圳市特区建工集团有限公司,广东 深圳 518118

深圳市综合交通与市政工程设计研究总院有限公司,广东 深圳 518003

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表面活性剂 复配 六价铬 土壤洗脱 土壤修复

2024

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
年,卷(期):2024.53(11)