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CO2流度控制用稠化剂性能评价

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为了解决低渗透油藏CCUS技术应用过程中由CO2 气窜导致的无效注气、驱油效率下降等问题,选用一种经过改性的苯基缩水甘油醚与环氧丙烷共聚合产物YCL-2,作为特低渗油藏CO2 增稠剂,采用可视化高压容器观察YCL-2 溶解性能,采用旋转流变仪研究了YCL-2 不同浓度及温度下的流变性能,并对YCL-2 在渗透率级差为 5和10 的岩心组中的驱替效果进行了考察,采用变径毛细管束模型模拟稠化剂体系计算不同渗透率岩心的封堵能力。结果表明,质量浓度2。0%以下的YCL-2 可完全溶解在超临界CO2 中;流变实验表明,温度升高会降低体系耐剪切性能;选择性注入实验表明,体系对岩心微小孔隙具有一定的封堵作用,适用于渗透率级差小于5 的油藏。
Performance evaluation of thickener for CO2 flow control
In order to solve the problems of ineffective gas injection and decreased oil displacement effi-ciency caused by CO2 gas channelling in the application of CCUS technology in low permeability reser-voir,YCL-2,a modified copolymerization product of phenyl glycidyl ether and propylene oxide,was select-ed as a CO2 thickener in extremely low permeability reservoir,and the solubility of YCL-2 was observed by visual high-pressure vessel.The rheological properties of YCL-2 at different concentrations and temper-atures were studied by rotating rheometer,and the displacement effect of YCL-2 in core groups with per-meability difference of 5 and 10 was investigated.The plugging ability of cores with different permeability was calculated by using varied-diameter capillary bundle model to simulate the thickener system.The re-sults show that YCL-2 with mass concentration below 2.0%can be completely dissolved in supercritical CO2.Rheological experiments show that the shear resistance of the system decreases with the increase of temperature.The selective injection experiment shows that the system has a certain sealing effect on the small pores of the core,and is suitable for reservoirs with permeability difference less than 5.

low permeability reservoirsthickener-carbon dioxidegas channelingpermeability ratiomobility

王维波、王锰、周艳、江绍静、郭茂雷、康宵瑜

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陕西延长石油(集团)有限责任公司研究院,陕西 西安 710065

陕西省二氧化碳封存与提高采收率重点实验室,陕西 西安 710065

陕西延长石油(集团)有限责任公司天然气研究院分公司,陕西 西安 710065

低渗透油藏 CO2稠化剂 气窜 渗透率级差 流度

2024

应用化工
陕西省石油化工研究设计院 陕西省化工学会

应用化工

CSTPCD北大核心
影响因子:0.411
ISSN:1671-3206
年,卷(期):2024.53(11)