首页|石墨相氮化碳基核壳异质结光催化材料的构筑及性能

石墨相氮化碳基核壳异质结光催化材料的构筑及性能

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光催化技术是解决能源危机和环境污染的有效途径,石墨相氮化碳(g-C3N4)被认为是一种有前途的光催化材料,但高载流子复合率严重限制了其光催化活性,通过构建核壳结构形成紧密且大面积接触的异质结,可有效促进光生载流子的分离效率。基于此,研究核壳结构的g-C3N4基异质结成为热点,通过介绍核壳结构的主要功能及核壳结构材料的应用,阐述g-C3N4基核壳异质结光催化剂的性能和优势,重点讨论g-C3N4基核壳异质结的构筑策略,包括水/溶剂热法、超声辅助自组装法、热处理法,并归纳总结合成过程中g-C3N4的生长机制,分析g-C3N4基核壳异质结光催化材料面临的挑战及未来发展方向,旨在为新型高效g-C3N4基核壳异质结光催化材料的设计与开发提供有益参考。
Construction and performance of g-C3N4-based core-shell heterojunction photocatalytic materials
Photocatalytic technique is an effective method to solve the problems of energy conversion and environmental remediation,and graphitic carbon nitride(g-C3N4)has been considered as a promising photocatalytic material.However,the high carrier recombination rate severely limits the photocatalytic activity of g-C3N4.Constructing core-shell structure to form heterojunction with tight connection interfaces and large contact area has proved to be an excellent strategy to improve the carrier separation efficiency.Therefore,the research on core-shell structured g-C3N4-based heterojunction photocatalysis becomes a hot spot.In this review,the main functions of core-shell structure and the applications of core-shell structured materials are introduced.The performance and advantages of g-C3N4-based core-shell heterojunction photocatalytic materials are elaborated.The preparation methods of core-shell structured g-C3N4-based heterojunctions and the growth mechanism of g-C3N4 in the synthetic process are emphatically discussed.Finally,challenges and perspectives for the future research and development of g-C3N4-based core-shell heterojunctions are analyzed.This review will provide guidance for the development of new and efficient g-C3N4-based core-shell structured photocatalytic materials.

photocatalysisg-C3N4heterojunctioncore-shell structure

郭彪、王贤雨、李施慧、刘芯辛

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沈阳师范大学化学化工学院,辽宁沈阳 110034

光催化 石墨相氮化碳 异质结 核壳结构

国家自然科学基金辽宁省自然科学基金沈阳师范大学大学生创新创业训练项目

222021352021-BS-157X202210166089

2024

陕西师范大学学报(自然科学版)
陕西师范大学

陕西师范大学学报(自然科学版)

CSTPCD北大核心
影响因子:0.563
ISSN:1672-4291
年,卷(期):2024.52(1)
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