中国石油大学学报(自然科学版)2024,Vol.48Issue(6) :85-94.DOI:10.3969/j.issn.1673-5005.2024.06.009

盐岩地层矿物离子对水泥浆性能的影响规律

Influence of mineral ions in salt stratum on properties of cement slurry

何斌斌 柳华杰 郑若臣 步玉环 殷慧 霍美桦 张军义 马小龙
中国石油大学学报(自然科学版)2024,Vol.48Issue(6) :85-94.DOI:10.3969/j.issn.1673-5005.2024.06.009

盐岩地层矿物离子对水泥浆性能的影响规律

Influence of mineral ions in salt stratum on properties of cement slurry

何斌斌 1柳华杰 2郑若臣 3步玉环 2殷慧 2霍美桦 2张军义 4马小龙5
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作者信息

  • 1. 中国石油大学(华东)石油工程学院,山东青岛 266580;中石化华北石油工程有限公司技术服务公司,河南郑州 450042
  • 2. 中国石油大学(华东)石油工程学院,山东青岛 266580
  • 3. 中国石油长庆油田分公司油气工艺研究院,陕西西安 710021
  • 4. 中石化华北石油工程有限公司技术服务公司,河南郑州 450042
  • 5. 中石化中原石油工程有限公司固井公司,河南濮阳 457001
  • 折叠

摘要

盐岩地层,特别是大段盐岩地层,富含的Na+、Ca2+、Mg2+等无机盐离子,固井期间通过溶解、扩散进入水泥浆,会诱发水泥浆API性能改变,不利于固井安全和固井质量.以某储气库钻遇的盐岩地层为对象,通过能谱分析盐岩地层的矿物离子类型及含量,明确盐岩地层主要的无机盐种类;试验评价单一无机盐、复合无机盐对固井水泥浆API性能的影响规律.结果表明:单一无机盐会诱发水泥浆的某一项或几项API性能指标不符合标准要求,而复合无机盐对水泥浆各项性能指标均产生不利影响;加入NaCl∶CaSO4∶MgCl2=42∶50∶8(质量比)的复合无机盐,水泥浆稠化时间、流变性能变化最突出,稠化时间降幅达55.0%,稠度系数增加1 260.5%;加入NaCl∶CaSO4∶MgCl2=88∶10∶2 的复合无机盐,水泥浆滤失量、抗压强度变化最显著,滤失量增加 58.2 mL,增幅 158.2%,抗压强度损失 9.0 MPa,降幅达 38.3%;含有一定比例MgCl2 的盐岩地层固井,应注重水泥浆稠化时间、流变参数、抗压强度性能的优化;含有一定比例CaSO4 的盐岩地层固井,应强化水泥浆滤失量的优化.

Abstract

Salt stratum,especially large thicknesses of salt stratum,are rich in inorganic salt ions such as Na+,Ca2+,Mg2+.They can enter the cement slurry through dissolution and diffusion during cementing,which will induce changes in the API performance of the cement slurry,and this is not conducive to cementing safety and quality.Taking the salt stratum drilled in a gas storage as the research object,the types and contents of mineral ions in salt stratum were analyzed by energy spectrum,and the main inorganic salt types in salt rock strata were determined.The influence of single type inorganic salt and compos-ite inorganic salt on the API performance of cementing cement slurry was evaluated by laboratory tests.The test results show that a single type of inorganic salt will cause one or more API performance of the cement slurry to fail to meet the standard re-quirements,while the composite inorganic salt will cause adverse effects on all performance indexes of the cement slurry.When the composite inorganic salt NaCl∶CaSO4∶MgCl2=42∶50∶8(mass ratio)is added to the cement slurry,the thickening time and rheological property change most significantly,in which the thickening time decreases by 55.0%,and the consistency coefficient increases by 1 260.5%.When the composite inorganic salt of NaCl∶CaSO4∶MgCl2=88∶10∶2 is added,the filtration loss and compressive strength change most significantly,in which the filtration loss increases by 58.2 mL,an increase of 158.2%,and the compressive strength loss is 9.0 MPa,a decrease of 38.3%.For salt stratum with a certain proportion of MgCl2,the cement slurry should pay attention to the optimization of thickening time,rheological parameters and compressive strength.For salt stratum with a certain proportion of CaSO4,cement slurry should strengthen the optimization of filtration.

关键词

固井/盐岩地层/水泥浆性能/氯化钠/硫酸钙/氯化镁

Key words

cementing/salt stratum/cement slurry performance/sodium chloride/calcium sulfate/magnesium chloride

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出版年

2024
中国石油大学学报(自然科学版)
中国石油大学

中国石油大学学报(自然科学版)

CSTPCDCSCD北大核心
影响因子:1.169
ISSN:1673-5005
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