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有机金属超滤膜除油技术研究

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有机金属超滤膜在进行油水分离过滤时,良好的亲水憎油性使得有机金属膜具有抗污染、不易污堵的特性.在开展的除油试验中,有机金属超滤膜除油装置在30LMH的膜通量下可稳定运行1个月以上,且石油类和SS去除率平均分别达76.8%和76.6%,产水石油类、SS稳定达标,最高仅分别为10.3mg/L、23mg/L,低于气浮工艺出水指标要求近50%.有机金属超滤膜除油装置在40LMH的膜通量下,运行难度增加,通过CEB与CIP联合清洗可有效延长膜的稳定运行周期,保证系统的稳定运行.在30LMH的膜通量下有机金属超滤膜工艺可替代传统的气浮处理工艺.
RESEARCH ON OIL REMOVAL TECHNOLO-GY BY ORGANIC METAL ULTRAFILTRATION MEMBRANE
Organic metal ultrafiltration membranes have good hydrophilicity and hydrophobicity during oil-water separation and filtration,which make them resistant to pollution and less prone to clogging.In the oil removal experiment conducted by using organic metal ultrafiltration membrane,the oil removal device using organic metal ultrafiltration membrane can oper-ate stably for more than one month at a membrane flux of 30LMH,and the average removal rates of petroleum and SS are 76.8%and 76.6%respectively.The pro-duced water for petroleum and SS is stable and meets the standards,with the highest being only 10.3mg/L and 23mg/L respectively,which is nearly 50%lower than the effluent indicators required by the air flotation pro-cess.The operation difficulty of the oil removal device using organic metal ultrafiltration membrane increases at a membrane flux of 40LMH.The combined cleaning of CEB and CIP can effectively extend the stable oper-ation cycle of the membrane and ensure the stable op-eration of the system.The organic metal ultrafiltration membrane process can replace the traditional air flota-tion treatment process at a membrane flux of 30LMH.

organic metal materialsultrafiltrationoil removal

倪福功、王国栋

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中国石油化工股份有限公司天津分公司,天津 300270

有机金属材质 超滤 除油

2024

石油化工安全环保技术
中国石化工程建设有限公司

石油化工安全环保技术

影响因子:0.339
ISSN:1673-8659
年,卷(期):2024.40(3)
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