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减少大型低温乙烯球罐预冷过程中VOCs排放

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对某石化企业乙烯罐区3000m3低温乙烯球罐预冷过程的工艺操作进行了简要介绍,针对乙烯球罐需要预冷至-30℃以下才能接料投用的苛刻工艺条件及预冷操作的技术难题和安全环保风险,在理论分析可行的基础上,提出将预冷方式由"插底管进液"改为"顶部喷洒液滴".实践证明,顶部喷洒液滴的预冷方式将球罐预冷时间由56h缩短至12h,减少了乙烯等挥发性有机物(VOCs)向火炬排放约30t,实现了碳减排和清洁生产目的.同时,也消除了因罐顶与罐底温差大导致球罐材质发生脆裂泄漏而引发的安全环保风险.
REDUCE VOCS EMISSIONS DURING PRE-COOLING OF LARGE LOW-TEMPERA-TURE ETHYLENE STORAGE TANKS
In view of the harsh process conditions of ethylene spherical tank that needs to be pre-cooled to below-30 ℃ before receiving materials and the safety and environmental protection risks of the pre-cooling operation,on the basis of theoretical analysis and feasi-bility,it is proposed to change the pre-cooling method from"bottom tube inlet"to"top spraying droplets"in view of the harsh process conditions of ethylene spher-ical tank that need to be pre-cooled to below-30 ° C before receiving materials and putting them into use.It has been proved in practice that the pre-cooling method of spraying droplets on the top shortens the pre-cooling time of the spherical tank from 56 hours to 12 hours,reduces the emission of volatile organic compounds(VOCs)such as ethylene to the flare by about 30 tons,and achieves the purpose of carbon emission reduction and cleaner production.At the same time,it also elim-inates the safety and environmental protection risks caused by the brittle leakage of spherical tank material caused by the large temperature difference between the top and bottom of the tank.

Low-temperature ethylene spherical tankPre-coolingDifference of temperatureBrittle leakageVOCs

李翠芳

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榆林市生态环境局横山分局(横山区环境监测站),陕西榆林 719000

低温乙烯球罐 预冷 温差 脆裂泄漏 VOCs

2024

石油化工安全环保技术
中国石化工程建设有限公司

石油化工安全环保技术

影响因子:0.339
ISSN:1673-8659
年,卷(期):2024.40(4)