石油化工腐蚀与防护2024,Vol.41Issue(2) :43-48.

聚乙烯醇装置醋酸提浓塔塔盘失效原因分析

Failure analysis of acetic acid concentration tower tray in polyvinyl alcohol plant

曹振兴
石油化工腐蚀与防护2024,Vol.41Issue(2) :43-48.

聚乙烯醇装置醋酸提浓塔塔盘失效原因分析

Failure analysis of acetic acid concentration tower tray in polyvinyl alcohol plant

曹振兴1
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作者信息

  • 1. 中石化炼化工程集团洛阳技术研发中心,河南洛阳 471003;中国石化石油化工设备防腐蚀研究中心,河南洛阳 471003
  • 折叠

摘要

醋酸提浓塔作为聚乙烯醇回收工段的关键设备,担负着醋酸回用生产系统的使命.但由于塔内醋酸腐蚀环境恶劣,即使现役材质耐蚀等级提升到钛材,设备面临的腐蚀问题仍旧表现突出,也造成装置的运行周期缩短和经济效益下降.该研究在现场腐蚀调研的基础上,通过采用材质元素分析、扫描电镜(SEM)和X射线衍射(XRD)等方法,分析研究了 TA2塔盘失效的原因、过程及其腐蚀防护措施.结果表明:TA2的腐蚀与氢脆是导致醋酸提浓塔塔盘失效的主要成因;醋酸提浓塔的腐蚀环境为醋酸+氯离子,其中,氯离子在塔内的富集加剧了醋酸的腐蚀.提出材料升级与工艺腐蚀控制是醋酸提浓塔优选防护研究方向.

Abstract

As a key equipment in polyvinyl alcohol recovery section,acetic acid concentration tower plays an important role of re-cycling acetic acid in production system.However,due to the harsh acetic acid corrosion environment inside the tower,even if the anti-corrosion level of present material is upgraded to titanium,corrosion problem still remains prominent,thus leads to a shortened operating cycle of the plant and a decrease in economic benefits.On the basis of on-site corrosion investigation,cau-ses,processes and corrosion protections of TA2 tray failure were studied by applying methods such as material element analysis,scanning electron microscopy(SEM)and X-ray diffraction(XRD).The findings indicated that TA2 corrosion and hydrogen em-brittlement are main causes.Corrosion environment at the corrosion site of acetic acid concentration tower is acetic acid+chlo-ride ions.The enrichment of chloride ions in the tower accelerates the corrosion of acetic acid.Material upgrading and process corrosion control were suggested as the research direction for acetic acid concentration tower.

关键词

聚乙烯醇/提浓塔/醋酸腐蚀/钛材/塔盘

Key words

polyvinyl alcohol/concentration tower/acetic acid corrosion/titanium material/tray

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出版年

2024
石油化工腐蚀与防护
中国石化集团洛阳石化工程公司

石油化工腐蚀与防护

影响因子:0.327
ISSN:1007-015X
参考文献量12
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