石油化工腐蚀与防护2024,Vol.41Issue(3) :39-44.

纳米硅酸锂杂化聚合物在石化混凝土修复中的应用

Application of nano-lithium silicate hybrid polymer in petrochemical concrete repair

秦峰 吴士云 高原 姚增祥 张猛 李晓炜
石油化工腐蚀与防护2024,Vol.41Issue(3) :39-44.

纳米硅酸锂杂化聚合物在石化混凝土修复中的应用

Application of nano-lithium silicate hybrid polymer in petrochemical concrete repair

秦峰 1吴士云 1高原 2姚增祥 2张猛 3李晓炜3
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作者信息

  • 1. 中国石化上海石油化工股份有限公司,上海 200540
  • 2. 上海奇想青晨新材料科技股份有限公司,上海 200540
  • 3. 中石化炼化工程集团洛阳技术研发中心,河南洛阳 471003
  • 折叠

摘要

混凝土是石化企业设备中最常用、最经济的建筑结构材料,然而随着服役年限的增加,带来了安全风险并影响企业外观形象,高质量保护层是提高钢筋混凝土耐久性的重要措施.基于聚合物纳米超支化关键技术,制备了混凝土防碳化材料,设计形成"纳米带锈转锈底漆/反应型渗透封闭底漆+防碳化中间填充层+防碳化耐候面漆"体系方案及配套的施工技术,在石化企业沉淀池外壁的应用结果表明,混凝土修复层表面平整美观、无明显外观缺陷,干膜厚度满足设计要求,修复层抗压强度≥35 MPa,附着力≥1.5 MPa,未发生碳化现象.此外,纳米硅酸锂杂化聚合物防碳化体系为水性体系,减少了 VOC排放,环保效果明显,具有良好的社会效益.

Abstract

Concrete is the most commonly used and economical building structural material in petrochemical equipment.Howev-er,more safety problems are being faced along with the increasing service life.High quality protective layer is an important meas-ure to improve durability of reinforced concrete.Based on key technology of hyperbranched polymer,concrete anti-carbonization material was prepared,and a set of system scheme and supporting construction technology of"nano rust-to-rust primer/reactive penetration sealing primer+anti-carbonization middle filling layer+anti-carbonization weathering resistance topcoat"was de-signed.The experimental results on outer wall of sedimentation tanks in petrochemical enterprise showed that the surface of con-crete repair layer is flat with no obvious defects,dry film thickness is capable of achieving design requirement,compressive strength of repair layer≥35 MPa,adhesion ≥ 1.5 MPa,no carbonization phenomenon occurs.In addition,nano-lithium sili-cate hybrid polymer anti-carbonization system is water-based system that reduces VOC emissions,brings significant environmental protection effects and achieves good social benefits.

关键词

混凝土修复/超支化聚合物/防碳化涂层/耐候性

Key words

concrete repair/hyperbranched polymer/anti-carbonization coating/weathering resistance

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基金项目

中国石化科技开发项目(321130)

出版年

2024
石油化工腐蚀与防护
中国石化集团洛阳石化工程公司

石油化工腐蚀与防护

影响因子:0.327
ISSN:1007-015X
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